Green Deep Eutectic Solvents

Berdimurodov Elyor, PhD is an Associate Professor at the National University of Uzbekistan, Tashkent, University. He has published five books, 50 book chapters, and more than 200 articles in international journals. His research areas include corrosion science, electrochemistry, quantum chemistry, materials science, green chemistry, and nanochemistry. Chandrabhan Verma, PhD works at the Department of Chemical and Petroleum Engineering, Khalifa University of Science and Technology Abu Dhabi, United Arab Emirates. He is a member of the American Chemical Society and authors reviews studies for several journals. His research focuses on synthesizing and designing environmentally-friendly corrosion inhibitors for use in several industrial applications. Chaudhery Mustansar Hussain, PhD is an adjunct professor and Director of Laboratories in the Department of Chemistry and Environmental Sciences at the New Jersey Institute of Technology, USA. He has published numerous papers in peer-reviewed journals and more than 100 books. His research is focused on the applications of nanotechnology and advanced materials, environmental management, and analytical chemistry.

• Preface xv1 Green Deep Eutectic Solvents: Fundamental, Properties, and Applications 1Baiju Chenthamara, M. Shaibuna and Ramesh L. Gardas1.1 Introduction 21.2 History of DESs 31.3 Definition of DES 31.4 Classification 61.5 Preparation Methods 71.6 Characterization and Physicochemical Properties of DES 91.7 Selected Applications of DESs 231.8 Conclusions 262 Green Deep Eutectic Solvents: Green Synthesis, Fabrication, and Characterization 37Jyoti Chauhan, Ashwariya Patel, Rajesh Kumar Sahu, Shweta Kanungo and Bhawana Jain2.1 Introduction 382.2 Significance of DESs 382.3 Synthesis of Deep Eutectic Solvents (DESs) 392.4 Physicochemical Characteristics of DESs 402.5 Applications of DES 482.6 Application of DESs in Dermal and Transdermal Drug Delivery 512.7 Conclusion 523 Green Deep Eutectic Solvents: Structure, Toxicity, and Biodegradability 57Nübar Abbaszada, Nurevþan Kaya, Serap Cetinkaya and Burak Tüzün3.1 Introduction 573.2 Deep Eutectic Solvents: Overview and Classification 583.3 Toxicity and Biodegradability of NADES 643.4 Physicochemical Properties of Deep Eutectic Solvents 653.5 Application of NADES 683.6 Conclusion 694 Hydrophobic and Natural Deep Eutectic Solvents: Structure, Properties, and Application 75Khasan Berdimuradov, Akbarali Rasulov, Elyor Berdimurodov, Omar Dagdag, Mohamed Rbaa and Anvar Khamidov4.1 Introduction 764.2 Structure of Hydrophobic and Natural DES 774.3 Properties of Hydrophobic and Natural DES 804.4 Applications of Hydrophobic and Natural DES 874.5 Future Perspectives and Challenges 954.6 Conclusion 975 Green Deep Eutectic Solvents in Catalysis 103Husan Yaxshinorov, Javokhir Abdisattorov, Marcin Karbarz, Elyor Berdimurodov and Anvar Khamidov5.1 Introduction 1045.2 Applications of DES in Catalysis 1055.3 Mechanisms and Theoretical Studies 1125.4 Challenges and Limitations, and Future Perspectives 1155.5 Conclusion 1166 Green Deep Eutectic Solvents in Separation 121Yusufboy Rajabov, Jaykhun Mamatov, Laziz Azimov, Abhinay Thakur, Ashish Kumar, Elyor Berdimurodov and Anvar Khamidov6.1 Introduction 1226.2 Applications of DES in Extraction Processes 1246.3 DES in Separation of Biomolecules 1256.4 DES in Gas Separation 1286.5 DES in Membrane Separation Processes 1316.6 Challenges, Limitations, and Future Perspectives 1326.7 Conclusion 1347 Green Deep Eutectic Solvents in Gas Capture 141Khasan Berdimuradov, Muslum Demir, Elyor Berdimurodov, Omar Dagdag, Anvar Khamidov and Mohamed Rbaa7.1 Introduction 1427.2 Mechanisms of Gas Capture Using DES 1437.3 Applications of DES in Gas Capture 1457.4 Challenges and Future Perspectives 1517.5 Conclusion 1538 Green Deep Eutectic Solvents in Biocatalysis and Bioprocessing 157Ilayda Bersu Kul, Parham Taslimi, Nastaran Sadeghian, Gamze Tüzün and Burak Tüzün8.1 Description of Green Deep Eutectic Solvents 1598.2 Biocatalysis and Its Role in Bioprocesses 1608.3 Properties of Green Deep Eutectic Solvents 1628.4 Applications of DESs in Polar Organometallic Chemistry 1638.5 Applications of DESs in Metal-Catalyzed Reactions 1648.6 Applications of DESs in Biocatalysis 1658.7 Reactions Catalyzed by Lewis Acid Type DESs 1668.8 Reactions Catalyzed by Brønsted Acid Type DESs 1678.9 Combining Deep Eutectic Solvents with Enzymes to Create a Potent Toolbox for Organic Synthesis 1698.10 Whole-Cells Catalyzed Reductions 1718.11 Utilizing Deep Eutectic Solvents to Synthesize Green Nanoparticles and Their Use in Water Treatment 1728.12 DES as Solvent for Whole-Cell Biocatalysis 1748.13 DES as Extractive Agents in Biotransformation 1758.14 DESs Function in Biomass Pretreatment 1768.15 Future Perspectives 1768.16 Conclusion 1779 Green Deep Eutectic Solvents in Power Systems and Battery Technologies 183Halil Ýbrahim Çetintaþ and Burak Tüzün9.1 Introduction 1839.2 Fundamentals of DESs 1849.3 Classification of the DESs 1869.4 Properties of the DESs 1879.5 Applications of DESs 1899.6 DESs in Power Systems and Battery Technologies 1909.7 Conclusion 20010 Green Deep Eutectic Solvents in Organic Chemistry 209M. Rbaa, Z. Rouifi, M. Oubaaqa, A. Barrahi, E. Berdimurodov, B. Tüzün, B. Lakhrissi, A. Zarrouk and R. Seghiri10.1 Introduction 21010.2 Definition of Deep Eutectic Solvent 21210.3 Natural Deep Eutectic Solvents 21210.4 Methods for Preparing GDES 21410.5 Physicochemical Properties of Green Deep Eutectic Solvents 21410.6 Comparison with Traditional Solvents 21710.7 The Use of Green Deep Eutectic Solvents in Organic Chemistry 21810.8 Applications in Organic Synthesis 22010.9 Deep Eutectic Solvents Economic Advantages 22110.10 Conclusion 22211 Green Deep Eutectic Solvents in Genomics/Fundamentals of Nucleic Acids 227Ayushi Prajapat, Naina, Iona Massey, Prashant Singh, Garima Pandey, Kumar Rakesh Ranjan and Kamlesh Kumari11.1 An Introduction to Deep Eutectic Solvents 22811.2 Properties of Deep Eutectic Solvents 22811.3 General Applications of Deep Eutectic Solvents 22911.4 What are Green Deep Eutectic Solvents? 23611.5 Deep Eutectic Solvents with Biological Molecules 23711.6 Interaction of Deep Eutectic Solvents with Nucleic Acids (DNA/RNA) for Their Stability 24111.7 Conclusion 24312 Green Deep Eutectic Solvents in Pharmaceutical and Biomedical Applications 253Palesa Pamela Seele, Reitumetse Precious Molefi, Kabo Matshetshe, Hendriette Van der Walt and Charlotte Maserumule12.1 Introduction of DES to the Pharmaceutical and Medical Industry 25412.2 Biocompatibility, Cytotoxicity and Biodegradability of DES 26012.3 Biomedical Applications of DES 27112.4 Antimicrobial Properties and Mechanisms of DES 27812.5 Fabrication of DES to Improve the Drug Delivery Systems and Pharmacokinetics of Drugs 28112.6 The Mechanisms of DES in Solubilizing Biomolecules and the Effects of Water 29012.7 Industrial/Commercial Use and Limitations of DES 30313 Green Deep Eutectic Solvents in Nanomaterial Synthesis 327Abhinay Thakur and Ashish Kumar13.1 Introduction 32813.2 Fundamentals of Green Deep Eutectic Solvents 33013.3 Properties and Advantages of Green Deep Eutectic Solvents 33313.4 Interactions Between Green Deep Eutectic Solvents and Nanomaterial Precursors 33513.5 Applications of Green Deep Eutectic Solvents in Nanomaterial Synthesis 33813.6 Challenges and Future Perspectives 34413.7 Conclusion 34514 Green Deep Eutectic Solvents in Polymerization/Polymer Chemistry 355Omar Dagdag, Rajesh Haldhar, Abhinay Thakur, Walid Daoudi, Avni Berisha, Elyor Berdimurodov, Hicham Es-soufi and Hansang Kim14.1 Introduction 35614.2 General Description of DES 35814.3 DES: Their Role in Polymer Synthesis 35914.4 Study on Polymerization in DES 36014.5 Applications of DES in Polymer Chemistry 36414.6 Conclusion 36615 Green Deep Eutectic Solvents in the Extraction of Bioactive Compounds 371Elyor Berdimurodov, Ashish Kumar, Omar Dagdag, Mohamed Rbaa, Anvar Khamidov and Bhawana Jain15.1 Introduction 37215.2 Applications in Bioactive Compound Extraction 37415.3 Challenges and Future Directions in DES-Based Extraction 38215.4 Conclusion 38516 Green Deep Eutectic Solvents in Metallurgy and Electrodeposition 391Javokhir Abdisattorov, Akbarali Rasulov, Husan Yaxshinorov, Fan Baomin and Elyor Berdimurodov16.1 Introduction 39216.2 DES as Electrolytes in Metallurgy 39316.3 Green Deep Eutectic Solvents in Electrodeposition 39416.4 Challenges and Future Perspectives 40116.5 Conclusion 403References 403Index 407