Wide World of Adhesion

Anil N. Netravali, PhD is a retired educator who has been working in the field of polymer composites since 1984. He has published over 175 refereed journal articles and book chapters and edited or co-edited 6 books in the wide areas of fiber and resin interface characterization and control through fiber surface modification and resin modification using nanoparticles and nanofibrils. In the past 25 years, he has made significant contributions in the area of biodegradable green resins, composites, and nanocomposites that are fully derived from plants. Frank M. Etzler, PhD is a retired researcher and professor specializing in surface chemistry. He has more than 60 publications including book chapters and articles in international journals and conferences of repute. With more than 40 years of professional experience, his research has focused on adhesion science, powder compaction, and powder technology.

• Preface xxiiiDedication 1A Personal Tribute to Dr. Kash Mittal 21Half-a-Century Romance with Adhesion Science 49Part 1: Contact Angle, Wettability and Adhesion 711 Application of Tadmor Equations to the Description of Wettability of Solid Surfaces 73Salvador Pérez-Huertas and Konrad Terpilowski1.1 Introduction 741.2 Surface Preparation and Plasma Activation 771.3 Impact of Hysteresis on Contact Angle Measurement 901.4 Conclusions 912 Spreading and Adhesion - The Two Sides of Wettability and Their Role in Multiphase Flow through Porous Media of Petroleum Reservoirs 97Dandina N. Rao and Bikash D. Saikia2.1 Background: Surface Science and Zisman's Seminal Contribution 982.2 Evidence of Zisman-Type Spreading in Solid-Liquid-Liquid (S-L-L) Systems 1002.3 The Need for Exploration of Zisman-Type Spreading in S-L-L Systems 1032.4 Consequences of Zisman-Type Spreading in Rock-Oil-Brine (S-L-L) Systems 1042.5 Fluid-Fluid Spreading Phenomenon in S-L-L Systems 1052.6 Summary and Conclusions 1113 Application of Integrated Analytical Approach (IAA) to the Investigation of Release and Permeation Processes of Active Substances from Ointments Using the Contact Angle Methodology 115D. Rossi, S. Banella, E. Vettorato, E. Franceschinis, G. Lazzari, S. Dall'Acqua and N. Realdon3.1 Introduction 1163.2 Experimental 1173.4 Summary and Conclusions 1404 Coffee-Stain Effect ‒ Evaporation of Wetting and Nonwetting Liquid Drops: A Critical Review 145Andrew Terhemen Tyowua, Augusta Ijeoma Ezekwuaku and Msugh Targema4.1 Introduction 1454.2 Evaporation of Wetting Liquid Drops: Mechanism of Coffee-Stain Formation 1464.3 Detrimental Effects and Suppression of Coffee-Stain Phenomenon 1484.4 Applications of Coffee-Stain Phenomenon 1614.5 Summary 164Part 2: Adhesion Aspects 1735 Controlling the Way Surfaces Interact and Adhere in Cosmetics. From Polymers to Biophysical and Dermatological Applications 175Gustavo S. Luengo5.1 Introduction 1765.2 Hair Care and Surface Forces 1775.3 Skin Care and Adhesion 1815.4 Summary 1875.5 Acknowledgments 1896 Role of Surface Topography in Engineering Interfacial Adhesion: Fundamentals, Advancements and Prospects 195Anubha Jaiswal and Ravi P. Jaiswal6.1 Introduction 1966.2 Basics of Surface Topography 1976.3 Fundamentals of Adhesion Involving Solid Surfaces 2046.4 Experimental Measurements 2146.5 Applications of Topographical Modifications to Engineer Interfacial Adhesion 2206.6 Challenges and Future Perspectives 2236.7 Summary 2247 Adhesion Aspects in Color Cosmetics 231Hy Si Bui7.1 Introduction 2327.2 Principles of Adhesion in Cosmetics 2337.3 Factors Affecting Cosmetic Adhesion - The Role of Substrate 2377.4 Factors Affecting Cosmetic Adhesion – Cosmetic Ingredients 2477.5 Techniques to Measure Cosmetic Product Adhesion and Performance 2547.6 Factors Affecting Cosmetic Adhesion – Cosmetic Formulation 2617.7 Challenges and Future Directions for Long-Wear Color Cosmetics 2867.8 Summary 2878 Investigation on the Adhesion of Electrospun Polyacrylonitrile (PAN) Nanofiber Mats to Polypropylene (PP) Nonwoven Substrate 299Zaynab Daneshzand, Somaye Akbari, Parastoo Saeedi and Mohsen Mohseni8.1 Introduction 3008.2 Materials and Methods 3038.3 Results and Discussion 3058.4 Conclusions 3079 Microplastic Adhesion at Secondary Minimum in Porous Media: The Role of Hydration Forces 313Gang Chen10 Use of Plasma Technology to Improve Polymer Adhesion Part 1 Plasma Surface Modification to Enhance Polymer Adhesion 323Jörg Florian Friedrich10.1 Introduction 32410.2 Ways to High and Durable Adhesion by Polymer Surface Modification 32910.3 Principles of Metal-Polymer Adhesion 33310.4 Grafting of Molecules and Polymers on Monosort-Equipped Polyolefin Surfaces for Flexibilization of Interface 35310.5 Which Plasma Treatment Gives Maximum Adhesion? 36510.6 Summary 37411 Use of Plasma Technology to Improve Polymer Adhesion Part 2 Plasma Polymers as Adhesion Promoters 385Jörg Florian Friedrich11.1 Introduction 38511.2 Possible Uses of Plasma Polymers Despite Their Chemically Irregular Structure 40611.3 Efficiency of Plasma Polymers as Adhesion Promoters 41111.4 Summary 42012 Surface Engineering for Enhanced Adhesion in Polymer Materials 429Ankit Rawal, Dipankar Pal and Sudarsan Neogi12.1 Introduction 43012.2 Fundamentals of Adhesion in Polymers 43112.3 Case Studies and Applications 44712.4 Prospects 46312.5 Summary 46412.6 Acknowledgements 46513 Interfacial Studies on Cellulose/Biopolymer Composites 469Merin Sara Thomas, Surya S. Nair, Sathaiah Gunaseelan, Prasanth K. S. Pillai, Gayathry Sreekumar, Sabu Thomas and Laly A. Pothen13.1 Introduction 46913.2 Biopolymer/Cellulose Composites 47113.3 Interfacial Properties 47313.4 Strategies for Interfacial Enhancement 48013.5 Applications 48213.6 Summary 48414 Fiber/Resin Interfacial Shear Strength (IFSS) in Composites: A Brief Review of Micromechanical Methods of IFSS Measurement 489Anil N. Netravali14.1 Introduction 49014.2 Fiber/Resin Interface Studies 49314.3 Single Fiber Composite (SFC) or Fragmentation Test 49414.4 Single Fiber Pull-Out Test 50314.5 Microbond Test (Microbead Test) 50714.6 Fiber Push-Out and Push-In Tests 51014.7 Summary and Concluding Remarks 514Part 3: Adhesives and Adhesive Joints 52115 Switchable Thermosets in the World of Adhesives 523Natanel Jarach, Rachel Avshalomov and Hanna Dodiuk15.1 Introduction 52415.2 Covalent Adaptable Networks – A Quick Overview 52415.3 Switchable Adhesives 53015.4 Summary 55616 Investigation of Pressure-Sensitive Adhesives Solely from Epoxidized Soybean Oil 565Yunfei Liang and Kaichang Li16.1 Introduction 56616.2 Experimental 56716.3 Testing 57016.4 Results and Discussion 57216.5 Conclusions 58116.6 Acknowledgement 58117 Wood Adhesion and Wood Adhesives: What Remains to Be Investigated? 585Manfred Dunky17.1 Introduction 58517.2 Basics of Wood Bonding 58617.3 Bio-Based Wood Adhesives 60017.4 "Ecologically-Correct" (Synthetic) Adhesives, such as Aminoplastic Wood Adhesives Based on "Green Hydrogen" 60117.5 Activation of the Surface, Binderless Boards, Activation of Wood-Inherent Chemicals as Adhesives (Lignin, Carbohydrates/Hemicellulose) 60217.6 Binderless Boards, Activation of Wood-Inherent Adhesives (Lignin, Carbohydrates = Mainly Hemicellulose) 60617.7 Covalent Chemical Bonding between Wood Surface and Adhesive 60717.8 Citric Acid 60817.9 Simulation of the Hot-Press Process 60917.10 Use of Wood-Based Panels (WBPs) in Construction, Resistance against Swelling and Shrinking, Elasticity of the Bondline 61017.11 Denaturation and Thermal Treatment of Proteins 61117.12 Tailor-Made Wooden Products (Functional Boards) 61217.13 Recycling and Debonding 61417.14 Summary 61518 Soy Protein Structures and Wood Adhesive Performance Properties 623Charles R. Frihart18.1 Background 62418.2 Protein Structure 62418.3 Wood Adhesive Bond Strength 62718.4 Soy Dispersion Rheology 63018.5 Protein Structure Revisited 63318.6 Conclusion 63518.7 Summary 63619 Advances in Dental Adhesives: Current Innovations, Challenges, and Future Directions 643Isadora Martini Garcia, Lamia Sami Mokeem, Abdulrahman A. Balhaddad, Fabrício Mezzomo Collares and Mary Anne S. Melo19.1 Introduction 64419.2 Understanding the Challenges of Dental Adhesives inside the Mouth 64619.3 A Brief History of Dental Adhesives: From Innovation to Evolution 64819.4 Classification and Composition of Adhesive Systems 64919.5 New Approaches Targeting the Longevity of Adhesive-Dentin Interfaces 65719.6 Dental Adhesives Loaded with Antibacterial Properties 65819.7 Recent Strategies for Antibacterial Dental Adhesives 66019.8 Summary 66220 Bioadhesives: Recent Advances and Biomedical Applications 669Megha Goyal and Nitu Bhatnagar20.1 Introduction 66920.2 Classification of Bioadhesives 67220.3 Bio-Inspired Adhesives Derived from Plants and Animals 67420.4 Mechanisms of Adhesion 67620.5 Applications 67820.6 Challenges and Limitations 68320.7 Future Directions 68421 Surface Matters: The Role of Treatment Techniques in Multi-Material Adhesive Bonding 691Mani Mohan Tiwari, Saleema Noormohammed, Dilip Kumar Sarkar and X.-Grant Chen21.1 Introduction 69221.2 Materials and Methods 69421.3 Structural Adhesive Bonding 69621.4 Conclusions 70821.5 Acknowledgments 70922 Properties of Adhesives for High-Temperature Applications: A Critical Review 713Momin Urooj Ahmed and S.K. Panigrahi22.1 Introduction 71422.2 Properties of Adhesives at Elevated Temperature 71522.3 Methodology 71822.4 Results and Discussion 72722.5 Summary and Conclusions 74323 Methods to Enhance the Mechanical Performance of FRP Composite Adhesive Joints 749Henrique F.M. de Queiroz and Mariana D. Banea23.1 Introduction 75023.2 Factors Affecting the Performance of Composite Adhesive Joints 75123.3 Methods to Increase the Mechanical Performance of FRP Composite Adhesive Joints 75323.4 Summary and Future Prospects 767Acknowledgements 768References 768Index 775