Smart Protective Coatings for Corrosion Control

Lingwei Ma is Associate Professor at University of Science and Technology Beijing, China. Her main research interests include self-healing smart coatings, corrosion inhibitor analysis, and corrosion mechanisms. She is the deputy director of “One Belt and One Road” Southeast Asia Field Scientific Observation and Research Station for Corrosion and Protection of Environmental Materials. Dawei Zhang is Professor at University of Science and Technology Beijing (USTB), China. His research interests are intelligent materials and technologies for corrosion control (e.g. smart protective coatings, microbial corrosion, and AI-driven corrosion research). He serves as Director of Office of International Affairs of USTB, Deputy Director of National Materials Corrosion and Protection Data Center and Associate Director of Beijing Advanced Innovation Center for Materials Genome Engineering. He is an elected Fellow of Association for Materials Protection and Performance and also the Chair of its International Advisory Council. He is also an Editor of the journal Corrosion Science.

• Foreword xviiPreface xix1 Fundamentals of Smart Corrosion Protection Coatings 11.1 Introduction of Corrosion Protection Coatings 11.1.1 Mechanisms of Corrosion Protection Coatings 21.1.2 Failure Type and Failure Mechanism of Corrosion Protection Coatings 31.2 Smart Self-healing Coatings 51.2.1 Intrinsic Self-healing Coating 51.2.1.1 Self-healing Based on Dynamic Bonds 61.2.1.2 Self-healing Based on Shape Memory Effect 61.2.2 Extrinsic Self-healing Coating 81.2.2.1 Self-healing Coating Based on Defect Filling 101.2.3 Characterization Methods of Self-healing Properties 141.3 Smart Self-reporting Coatings 161.4 Superhydrophobic Coatings 171.5 Conclusions 20References 202 Development of Thermally Activated Self-healing Coating 292.1 Introduction 292.2 Thermally Activated Self-healing Coatings to Simultaneously Recover the Corrosion-resistance and Adhesion Strength 292.3 Thermally Activated Self-healing Coatings Based on Dual Actions 432.4 Chapter Summary 63References 643 Development of Photothermally Activated Self-healing Coating 753.1 Introduction 753.2 Self-healing Coating Based on GO–CeO 2 Photothermal Fillers 753.3 Self-healing Coating Based on TiN–BTA@MSN Photothermal Filler 893.4 Self-healing Coating Based on PCL@TiN Photothermal Fillers 1093.5 Self-healing Coating Based on Fe 3 O 4 –MBT Photothermal Fillers 1233.6 Chapter Summary 138References 1394 Development of pH- and Redox-activated Self-healing Coating 1534.1 Introduction 1534.2 pH Responsive Self-healing Coating Based on the Synergistic Effect of Two Corrosion Inhibitors 1534.3 pH Responsive Self-healing Coating Based on rGO@MS-P-BTA 1764.4 Redox and Saline Responsive Self-healing Coating Based on PANI/BTA Nanocapsules 1884.5 Chapter Summary 201References 2035 Development of Ion Exchange Activated Self-healing Coating 2175.1 Introduction 2175.2 Ion Exchange Activated Self-healing Coating Using GO-LDH Fillers 2175.3 Chapter Summary 242References 2446 Development of pH-responsive and Metal Ion-responsive Self-reporting Coating 2516.1 Introduction 2516.2 pH-responsive Self-reporting Coatings Based on PhPh Indicator 2526.3 Metal Ion-responsive Self-reporting Coatings Based on CDs 2536.4 Metal Ion-responsive Self-reporting Coatings Based on UF/Phen Microcapsules 2796.5 Chapter Summary 294References 2967 Development of Mechanically Responsive Self-reporting Coating 3057.1 Introduction 3057.2 Mechanically Responsive Self-reporting Coating Based on DCF 3067.3 Chapter Summary 320References 3228 Development of Aging-Resistant Coating with Self-healing and Self-reporting Properties 3298.1 Introduction 3298.2 Aging-Resistant, Self-healing, and Self-reporting Smart Coatings Based on TA Additives 3328.3 Aging-Resistant Anticorrosion Coatings Based on TP Additives 3698.4 Chapter Summary 381References 3839 Development of Superhydrophobic Coating with Good Mechanical Durability and Self-healing Effect 3939.1 Introduction 3939.2 Preparation and Evaluation of Modified Nano SiO 2 /Epoxy Resin Superhydrophobic Coating 3949.3 Preparation and Evaluation of CNTs/Epoxy Resin Superhydrophobic Coating 4029.4 Shape Memory Self-healing Superhydrophobic Coating Based on SiO 2 –CNT Hybrids 4139.5 Superhydrophobic Self-healing Coating Based on CNTs/LDH Nanocontainers Loaded with Corrosion Inhibitors 4249.6 Chapter Summary 435References 43710 Investigation of the Self-healing Performance of Coatings Using Atmospheric Corrosion Monitor Technique 44510.1 Introduction 44510.2 Characterization Methods for Corrosion Protection Coatings 44610.3 Study of the Self-healing Behavior of Coatings Using ACM Technique 45010.4 Chapter Summary 475References 47811 Future Development Direction of Smart Anticorrosive Coatings 48511.1 Introduction 48511.2 Smart Self-healing Coatings 48511.3 Smart Self-reporting Coatings 49011.4 Superhydrophobic Coatings 49111.5 Application of Atmospheric Corrosion Monitor Technology in Smart Coating Design 493Index 495