Del i serien Handbook of Reagents for Organic Synthesis

Reagents for Silicon-Mediated Organic Synthesis

Name: Reagents for Silicon-Mediated Organic Synthesis
SKU: 9780470710234
Price: 1869 SEK
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Author: Philip L. Fuchs
ISBN: 9780470710234

Inbunden, Engelska, 2011

AvPhilip L. Fuchs

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Over the last three decades the importance of organosilicon chemistry has greatly increased because it has opened a number of new synthetic strategies. Silicon reagents are usually low-cost, versatile and allow a wide range of reactions. This is the first Handbook to compile essential Silicon containing reagents and makes use of the leading reagent database e-EROS. Another hot volume in the series Handbooks of Reagents for Organic Synthesis, this is a must-have resource for all synthetic chemists working in drug development and medicinal chemistry. For the selection the Editor focussed on three key synthetic approaches with the greatest impact:1. Use of silicon as a 'temporary tether' by unifying a reactive pair of functional groups and taking advantage of their template-biased intramolecular cyclization.2. The specific use of the silane functionality as a hetero t-butyl group, often colloquially referred to as the use of silicon as a 'fat proton'.3. The use of the Brook rearrangement as an 'anion relay stratagem'.A new feature in this Handbook is the reagent finder, an alphabetically organized lookup table arranged by organic functionality and specific structure of the silicon atom to which it is bound.

Produktinformation

Utgivningsdatum2011-11-14
Mått224 x 287 x 41 mm
Vikt2 586 g
FormatInbunden
SpråkEngelska
SerieHandbook of Reagents for Organic Synthesis
Antal sidor854
FörlagJohn Wiley & Sons Inc
ISBN9780470710234

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Organisk kemi inom Naturvetenskap och teknik

Philip Fuchs began his career at Purdue in 1973. Since that time, he has graduated an extended family of 55 Ph.D.s. His awards and honors include an Eli Lilly young faculty fellowship (1975), an Alfred P. Sloan fellowship (1977), a Pioneer in Laboratory Robotics award (1986), a Martin teaching award (1991), and being voted by the students as one of Top 10 Teachers in School of Science at Purdue (1991, 1993, 1995, 1996).Fuchs has consulted for Pfizer, and Eli Lilly, served on the editorial board of The Journal of Organic Chemistry, and is currently an executive editor for the Electronic Encyclopedia of Organic Reagents (e-EROS), an online dynamic encyclopedia published by John Wiley & Sons.

Preface xiii Introduction xvReagent Finder Table xxiiiShort Note on InChIs and InChIKeys xxxi3-Acetoxy-2-trimethylsilylmethyl-1-propene 1Allyl(2-chloroethyl)dimethylsilane 9Allyl Trichlorosilane 10Allyltrimethylsilane 14Allyltrimethylsilylzinc Chloride 24Ammonium Hexafluorosilicate 25Azidotrimethylsilane 26Benzene, [[Difluoro(trimethylsilyl)methyl]seleno] 33Benzene, [[Difluoro(trimethylsilyl)methyl]thio]- 36Benzene, [[(1E)-2-(Trimethylsilyl)ethenyl]seleno] 39Benzene, [[(1E)-2-trimethylsilyl)ethenyl]sulfonyl]- 422,1-Benzoxasilole, 1,3-Dihydro-1,1-dimethyl- 43N-Benzyl-N-(methoxymethyl)-Ntrimethylsilylmethylamine 441,2-Bis(t-butyldimethylsilyl)hydrazine 461,2-Bis(chlorodimethylsilyl)ethane 481,4-Bis(dimethylamino)-1,1,4,4-tetramethyldisilethylene 50Bis(1-methoxy-2-methyl-1-propenyloxy)dimethylsilane 51Bis(methylthio)(trimethylsilyl)methane 52[Bis(2-pyridyldimethylsilyl)methyl]lithium 541,3-Bis(triisopropylsilyl)propyne 56N,O-Bis(trimethylsilyl)acetamide 58(1E,3E)-1,4-Bis(trimethylsilyl)-1,3-butadiene 73Bis(ß-trimethylsilylethanesulfonyl)imide 74N,O-Bis(trimethylsilyl)hydroxylamine 75Bis[(trimethylsilyl)methyl]zinc 76Bis(trimethylsilyl) Peroxide 79Bis(trimethylsilyl) Selenide 82Bis(trimethylsilyl) Sulfide 83Bromomagnesium Hexamethyldisilazide 85(Bromomethyl)chlorodimethylsilane 85Bromotrimethylsilane 92(E)-1-Bromo-4-trimethylsilyl-1-buten-3-yne 100(Z)-2-Bromo-1-(trimethylsilyloxy)ethylene 1052-Bromo-3-trimethylsilyl-1-propene 106(1-Bromovinyl)trimethylsilane 109t-Butyldimethylchlorosilane 110t-Butyldimethylsilyl Cyanide 120(t-Butyldimethylsilyl)diphenylphosphine 1212-t-Butyldimethylsilyl-1,3-dithiane 122O-(t-Butyldimethylsilyl)hydroxylamine 124N-(t-Butyldimethylsilyl)-N-methyltrifluoroacetamide 125t-Butyldimethylsilyl Trifluoromethanesulfonate 127t-Butyldiphenylchlorosilane 1351-t-Butylthio-1-t-butyldimethyl-silyloxyethylene 1381-t-Butylthio-1-t-butyldimethylsilyloxypropene 141t-Butyl Trimethylsilylacetate 1473-Butyn-2-ol, 4-(Trimethylsilyl)- 148Chlorodiisopropylsilane 151Chlorodimethylsilane 156Chlorodimethylvinylsilane 157Chlorodiphenylsilane 162(Chloromethyl)dimethylphenylsilane 162(E)-(3-Chloro-1-methyl-1-propenyl)-trimethylsilane 1661-Chloro-1-methylsiletane 166Chlorotrimethylsilane 170Chlorotriphenylsilane 182Cyanotrimethylsilane 184Diazo(trimethylsilyl)methyllithium 191(Dibromomethyl)trimethylsilane 197Di-t-butylchlorosilane 198Di-t-butyldichlorosilane 201trans-1,1-Di-t-butyl-2,3-dimethylsilirane 207Di-t-butylsilyl Bis(trifluoromethanesulfonate) 209Dichlorodiisopropylsilane 222Dichlorodimethylsilane 2281,3-Dichloro-1,1,3,3-tetraisopropyldisiloxane 2301,1-Dichloro-2,2,2-trimethyl-1-phenyldisilane 233Dicyanodimethylsilane 2341,2-Diethoxy-1,2-bis(trimethylsilyloxy)ethylene 235N,N-Diethylaminodimethylsilane 237Diethyl[dimethyl(phenyl)silyl]aluminum 237Diiododimethylsilane 238Diisopropyl Chlorosilane, Polymer-supported 240Diisopropylsilyl Bis(trifluoromethanesulfonate) 241Dilithium Cyanobis(dimethylphenylsilyl)-cuprate 248(a,a-Dimethylallyl)trimethylsilane 252(2-Dimethylaminomethylphenyl)phenylsilane 253Dimethyl(phenyl)silane 254Dimethylphenylsilyllithium 2551,1-Dimethylsilacyclobutane 261Dimethylthexylsilyl Chloride 263Dimethylthexylsilyl Trifluoromethanesulfonate 2651,3,2-Dioxaborolane, 2-(Dimethylphenylsilyl)-4,4,5,5- tetramethyl-, 1,3,2-Dioxaborolane, 4,4,5,5-Tetramethyl- 2-(methyldiphenylsilyl)-, 1,3,2-Dioxaborolane, 4,4,5,5- Tetramethyl-2-(triphenylsilyl)- 270Diphenyldifluorosilane 276Disilane, 1,1,1,2,2,2-hexamethyl- 2781-Ethoxy-1-(trimethylsilyloxy)cyclopropane 285Ethoxy(trimethylsilyl)acetylene 289Ethyl Lithio(trimethylsilyl)acetate 293Ethyl (Methyldiphenylsilyl)acetate 295Ethyl 2-(Methyldiphenylsilyl)propanoate 296Ethyl Trimethylsilylacetate 297Fluorosilicic Acid 301Formamide, N-N,bis(trimethylsilyl)- 302Hexachlorodisilane 309Hexamethylcyclotrisiloxane 310Hexamethyldisiloxane 313Hexamethyldisilazane 317(Iodoethynyl)trimethylsilane 321(Iodomethyl)trimethylsilane 323Iodotrimethylsilane 325(E)-1-Iodo-3-trimethylsilyl-2-butene 3363-Iodo-2-trimethylsilylmethyl-1-propene 338Isocyanatotrimethylsilane 339Ketene t-Butyldimethylsilyl Methyl Acetal 3413-Lithio-1-triisopropylsilyl-1-propyne 347Lithium N-Benzyltrimethylsilylamide 349Lithium Bis[dimethyl(phenyl)silyl]cuprate 350Lithium Cyano(dimethylphenylsilyl)cuprate 353Lithium Hexamethyldisilazide 356Methanamine, 1,1-Bis(trimethylsilyl) 369Methanesulfonamide, 1,1,1-Trifluoro-N[(trifluoromethyl)sulfonyl]-N(trimethylsilyl)- 372(Methoxymethyl)bis(trimethylsilyl)amine 3741-Methoxy-2-methyl-1-(trimethylsilyloxy)propene 376N-Methyl-N,O-bis(trimethylsilyl)-hydroxylamine 380Methyldiphenylchlorosilane 381(Methylthio)trimethylsilane 388Methyltrichlorosilane 389Methyl Trichlorosilyl Ketene Acetal (1) 393Methyl 2-Trimethylsilylacrylate 3961-Methyl-1-(trimethylsilyl)allene 3972-Methyl-2-(trimethylsilyloxy)-3-pentanone 400PDMS Thimbles 403Phenylsilane–Cesium Fluoride 408(2-Phenylsulfonylethyl)trimethylsilane 409Phenylthiobis(trimethylsilyl)methane 411(Phenylthiomethyl)trimethylsilane 412(Phenylthio)trimethylsilane 4141-(Phenylthio)-1-(trimethylsilyl)cyclopropane 4181-Phenylthio-1-trimethylsilylethylene 4192-(Phenylthio)-2-(trimethylsilyl)propane 420Phenyl Trimethylsilyl Selenide 421Phosphine, Tris(trimethylsilyl)- 422Polymethylhydrosiloxane 427Potassium Hexamethyldisilazide 432(+)-9-(1S,2S-Pseudoephedrinyl)-(10R)-(trimethylsilyl)- 9-borabicyclo[3.3.2]decane 4532-Pyridyldimethylsilane 457Silane, 1,1-(Chloromethylene)bis[1,1,1]-trimethyl- 461Silane, Chlorotri-2-propen-1-yl- 463Silane, 1,1-(1-Propene-1,3-diyl)bis[1,1,1-trimethyl-(E)Silane, 1,1-(1-Propene-1,3-diyl)bis[1,1,1-trimethyl-(Z)Silane, 1,1-(1-Propene-1,3-diyl)bis[1,1,1- trimethyl-(E + Z) 464Sodium Hexamethyldisilazide 468Tetrabutylammonium Difluorotriphenylsilicate 4792,4,6,8-Tetraethenyl-2,4,6,8-tetramethylcyclotetrasiloxane 4843-Tetrahydropyranyloxy-1-trimethylsilyl-1-propyne 4871,1,3,3-Tetramethyldisilazane 4881,1,2,2-Tetraphenyldisilane 490Trialkylsilyl Cyanide, Polymer-supported 494Tribenzylchlorosilane 496Tri(t-butoxy)silanethiol 497(E)-1-Tri-n-butylstannyl-2-trimethylsilylethylene 499Trichloroiodosilane 500Triethoxysilane 501Triethylsilane 506Triethylsilyl Hydrotrioxide 5143-Triethylsilyloxy-1,4-pentadiene 515(a-Triethylsilyl)propionaldehyde Cyclohexylimine 516Triethylsilyl Trifluoromethanesulfonate 517Trimethylsilyl Trifluoromethanesulfonate 518Trifluoromethanesulfonic Acid, Chlorobis (1,1-Dimethylethyl)silyl Ester 537Trifluoromethyltrimethylsilane 539Triisopropylsilanethiol 546(Triisopropylsilyl)acetylene 550Triisopropylsilyl Chloride 554Triisopropylsilylethynyl Triflone 558Triisopropylsilyl Trifluoromethanesulfonate 559Trimethylsilylacetic Acid 562Trimethylsilylacetone 563Trimethylsilylacetonitrile 564Trimethylsilylacetylene 569(Trimethylsilyl)allene 580Trimethylsilylallyllithium 582(E)-1-Trimethylsilyl-1,3-butadiene 5853-Trimethylsilyl-3-buten-2-one 5869-[1-(Trimethylsilyl)-2(E)-butenyl] -9-borabicyclo[3.3.1]nonane 588Trimethylsilylcopper 589Trimethylsilyldiazomethane 590Trimethylsilyldiethylamine 5982-Trimethylsilyl-1,3-dithiane 6042-(Trimethylsilyl)ethanesulfonamide 609ß-Trimethylsilylethanesulfonyl Chloride 611[N-(2-(Trimethylsilyl)ethanesulfonyl)-imino]phenyliodane 6172-(Trimethylsilyl)ethanethiol 6182-(Trimethylsilyl)ethanol 6222-(Trimethylsilyl)ethoxycarbonylimidazole 6272-(Trimethylsilyl)ethoxymethyl Chloride 628[2-(Trimethylsilyl)ethoxymethyl]triphenylphosphonium Chloride 6332-(Trimethylsilyl)ethyl Chloroformate 6342-(Trimethylsilyl)ethyl 3-Nitro-1H-1,2,4-triazole-1-carboxylate 636(Trimethylsilyl)ethynylcopper(I) 637Trimethylsilyl Fluorosulfonyldifluoroacetate 638N-(Trimethylsilyl)imidazole 640Trimethylsilylketene 645Trimethylsilyllithium 650Trimethylsilyl Methanenitronate 6531-Trimethylsilyl-1-methoxyallene 656Trimethylsilylmethyl Azide 6571-[(Trimethylsilyl)methyl]-1H-benzotriazole 6582-Trimethylsilylmethyl-1,3-butadiene 6603-[(Trimethylsilyl)methyl]-3-butenoic Acid Methyl Ester 662Trimethylsilylmethyllithium 664Trimethylsilylmethylmagnesium Chloride 666Trimethylsilylmethylpotassium 6742-Trimethylsilylmethyl-2-propen-1-ol 6751-Trimethylsilyloxy-1,3-butadiene 6772-Trimethylsilyloxy-1,3-butadiene 6812-Trimethylsilyloxyfuran 684(Z)-2-(Trimethylsilyloxy)vinyllithium 6935-Trimethylsilyl-1,3-pentadiene 6952-(Trimethylsilyl)phenyl Triflate 697Trimethylsilylpotassium 7002-Trimethylsilyl-1,3-propanediol 7013-Trimethylsilyl-2-propen-1-yl Acetate 7033-Trimethylsilyl-1-propyne 7043-Trimethylsilyl-2-propynylcopper(I) 7112-(Trimethylsilyl)thiazole 712Trimethylsilyltributylstannane 7193-Trimethylsilyl-3-trimethylsilyloxy-1-propene 723(E)-1-Trimethylsilyl-2-trimethylstannylethylene 724(Trimethylsilyl)vinylketene 7251-(Trimethylsilyl)vinyllithium 726(E)-2-(Trimethylsilyl)vinyllithium 7291-(Trimethylsilyl)vinylmagnesium Bromide–Copper(I) Iodide 730Trimethyl{2-[(tributylstannyl)methyl]-2-propenyl}silane 731Triphenylsilane 733Tris(dimethylamino)sulfonium Difluorotrimethylsilicate 739Tris(trimethylsilyl)aluminum 745Tris(trimethylsilyl)methane 746Tris(trimethylsilyl)silane 747Vinyltrimethylsilane 755List of Contributors 763Reagent Formula Index 779Subject Index 785 ???

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Produktinformation

Utgivningsdatum2011-11-14
Mått224 x 287 x 41 mm
Vikt2 586 g
FormatInbunden
SpråkEngelska
SerieHandbook of Reagents for Organic Synthesis
Antal sidor854
FörlagJohn Wiley & Sons Inc
ISBN9780470710234

Tillhör följande kategorier

Organisk kemi inom Naturvetenskap och teknik

Preface xiii Introduction xvReagent Finder Table xxiiiShort Note on InChIs and InChIKeys xxxi3-Acetoxy-2-trimethylsilylmethyl-1-propene 1Allyl(2-chloroethyl)dimethylsilane 9Allyl Trichlorosilane 10Allyltrimethylsilane 14Allyltrimethylsilylzinc Chloride 24Ammonium Hexafluorosilicate 25Azidotrimethylsilane 26Benzene, [[Difluoro(trimethylsilyl)methyl]seleno] 33Benzene, [[Difluoro(trimethylsilyl)methyl]thio]- 36Benzene, [[(1E)-2-(Trimethylsilyl)ethenyl]seleno] 39Benzene, [[(1E)-2-trimethylsilyl)ethenyl]sulfonyl]- 422,1-Benzoxasilole, 1,3-Dihydro-1,1-dimethyl- 43N-Benzyl-N-(methoxymethyl)-Ntrimethylsilylmethylamine 441,2-Bis(t-butyldimethylsilyl)hydrazine 461,2-Bis(chlorodimethylsilyl)ethane 481,4-Bis(dimethylamino)-1,1,4,4-tetramethyldisilethylene 50Bis(1-methoxy-2-methyl-1-propenyloxy)dimethylsilane 51Bis(methylthio)(trimethylsilyl)methane 52[Bis(2-pyridyldimethylsilyl)methyl]lithium 541,3-Bis(triisopropylsilyl)propyne 56N,O-Bis(trimethylsilyl)acetamide 58(1E,3E)-1,4-Bis(trimethylsilyl)-1,3-butadiene 73Bis(ß-trimethylsilylethanesulfonyl)imide 74N,O-Bis(trimethylsilyl)hydroxylamine 75Bis[(trimethylsilyl)methyl]zinc 76Bis(trimethylsilyl) Peroxide 79Bis(trimethylsilyl) Selenide 82Bis(trimethylsilyl) Sulfide 83Bromomagnesium Hexamethyldisilazide 85(Bromomethyl)chlorodimethylsilane 85Bromotrimethylsilane 92(E)-1-Bromo-4-trimethylsilyl-1-buten-3-yne 100(Z)-2-Bromo-1-(trimethylsilyloxy)ethylene 1052-Bromo-3-trimethylsilyl-1-propene 106(1-Bromovinyl)trimethylsilane 109t-Butyldimethylchlorosilane 110t-Butyldimethylsilyl Cyanide 120(t-Butyldimethylsilyl)diphenylphosphine 1212-t-Butyldimethylsilyl-1,3-dithiane 122O-(t-Butyldimethylsilyl)hydroxylamine 124N-(t-Butyldimethylsilyl)-N-methyltrifluoroacetamide 125t-Butyldimethylsilyl Trifluoromethanesulfonate 127t-Butyldiphenylchlorosilane 1351-t-Butylthio-1-t-butyldimethyl-silyloxyethylene 1381-t-Butylthio-1-t-butyldimethylsilyloxypropene 141t-Butyl Trimethylsilylacetate 1473-Butyn-2-ol, 4-(Trimethylsilyl)- 148Chlorodiisopropylsilane 151Chlorodimethylsilane 156Chlorodimethylvinylsilane 157Chlorodiphenylsilane 162(Chloromethyl)dimethylphenylsilane 162(E)-(3-Chloro-1-methyl-1-propenyl)-trimethylsilane 1661-Chloro-1-methylsiletane 166Chlorotrimethylsilane 170Chlorotriphenylsilane 182Cyanotrimethylsilane 184Diazo(trimethylsilyl)methyllithium 191(Dibromomethyl)trimethylsilane 197Di-t-butylchlorosilane 198Di-t-butyldichlorosilane 201trans-1,1-Di-t-butyl-2,3-dimethylsilirane 207Di-t-butylsilyl Bis(trifluoromethanesulfonate) 209Dichlorodiisopropylsilane 222Dichlorodimethylsilane 2281,3-Dichloro-1,1,3,3-tetraisopropyldisiloxane 2301,1-Dichloro-2,2,2-trimethyl-1-phenyldisilane 233Dicyanodimethylsilane 2341,2-Diethoxy-1,2-bis(trimethylsilyloxy)ethylene 235N,N-Diethylaminodimethylsilane 237Diethyl[dimethyl(phenyl)silyl]aluminum 237Diiododimethylsilane 238Diisopropyl Chlorosilane, Polymer-supported 240Diisopropylsilyl Bis(trifluoromethanesulfonate) 241Dilithium Cyanobis(dimethylphenylsilyl)-cuprate 248(a,a-Dimethylallyl)trimethylsilane 252(2-Dimethylaminomethylphenyl)phenylsilane 253Dimethyl(phenyl)silane 254Dimethylphenylsilyllithium 2551,1-Dimethylsilacyclobutane 261Dimethylthexylsilyl Chloride 263Dimethylthexylsilyl Trifluoromethanesulfonate 2651,3,2-Dioxaborolane, 2-(Dimethylphenylsilyl)-4,4,5,5- tetramethyl-, 1,3,2-Dioxaborolane, 4,4,5,5-Tetramethyl- 2-(methyldiphenylsilyl)-, 1,3,2-Dioxaborolane, 4,4,5,5- Tetramethyl-2-(triphenylsilyl)- 270Diphenyldifluorosilane 276Disilane, 1,1,1,2,2,2-hexamethyl- 2781-Ethoxy-1-(trimethylsilyloxy)cyclopropane 285Ethoxy(trimethylsilyl)acetylene 289Ethyl Lithio(trimethylsilyl)acetate 293Ethyl (Methyldiphenylsilyl)acetate 295Ethyl 2-(Methyldiphenylsilyl)propanoate 296Ethyl Trimethylsilylacetate 297Fluorosilicic Acid 301Formamide, N-N,bis(trimethylsilyl)- 302Hexachlorodisilane 309Hexamethylcyclotrisiloxane 310Hexamethyldisiloxane 313Hexamethyldisilazane 317(Iodoethynyl)trimethylsilane 321(Iodomethyl)trimethylsilane 323Iodotrimethylsilane 325(E)-1-Iodo-3-trimethylsilyl-2-butene 3363-Iodo-2-trimethylsilylmethyl-1-propene 338Isocyanatotrimethylsilane 339Ketene t-Butyldimethylsilyl Methyl Acetal 3413-Lithio-1-triisopropylsilyl-1-propyne 347Lithium N-Benzyltrimethylsilylamide 349Lithium Bis[dimethyl(phenyl)silyl]cuprate 350Lithium Cyano(dimethylphenylsilyl)cuprate 353Lithium Hexamethyldisilazide 356Methanamine, 1,1-Bis(trimethylsilyl) 369Methanesulfonamide, 1,1,1-Trifluoro-N[(trifluoromethyl)sulfonyl]-N(trimethylsilyl)- 372(Methoxymethyl)bis(trimethylsilyl)amine 3741-Methoxy-2-methyl-1-(trimethylsilyloxy)propene 376N-Methyl-N,O-bis(trimethylsilyl)-hydroxylamine 380Methyldiphenylchlorosilane 381(Methylthio)trimethylsilane 388Methyltrichlorosilane 389Methyl Trichlorosilyl Ketene Acetal (1) 393Methyl 2-Trimethylsilylacrylate 3961-Methyl-1-(trimethylsilyl)allene 3972-Methyl-2-(trimethylsilyloxy)-3-pentanone 400PDMS Thimbles 403Phenylsilane–Cesium Fluoride 408(2-Phenylsulfonylethyl)trimethylsilane 409Phenylthiobis(trimethylsilyl)methane 411(Phenylthiomethyl)trimethylsilane 412(Phenylthio)trimethylsilane 4141-(Phenylthio)-1-(trimethylsilyl)cyclopropane 4181-Phenylthio-1-trimethylsilylethylene 4192-(Phenylthio)-2-(trimethylsilyl)propane 420Phenyl Trimethylsilyl Selenide 421Phosphine, Tris(trimethylsilyl)- 422Polymethylhydrosiloxane 427Potassium Hexamethyldisilazide 432(+)-9-(1S,2S-Pseudoephedrinyl)-(10R)-(trimethylsilyl)- 9-borabicyclo[3.3.2]decane 4532-Pyridyldimethylsilane 457Silane, 1,1-(Chloromethylene)bis[1,1,1]-trimethyl- 461Silane, Chlorotri-2-propen-1-yl- 463Silane, 1,1-(1-Propene-1,3-diyl)bis[1,1,1-trimethyl-(E)Silane, 1,1-(1-Propene-1,3-diyl)bis[1,1,1-trimethyl-(Z)Silane, 1,1-(1-Propene-1,3-diyl)bis[1,1,1- trimethyl-(E + Z) 464Sodium Hexamethyldisilazide 468Tetrabutylammonium Difluorotriphenylsilicate 4792,4,6,8-Tetraethenyl-2,4,6,8-tetramethylcyclotetrasiloxane 4843-Tetrahydropyranyloxy-1-trimethylsilyl-1-propyne 4871,1,3,3-Tetramethyldisilazane 4881,1,2,2-Tetraphenyldisilane 490Trialkylsilyl Cyanide, Polymer-supported 494Tribenzylchlorosilane 496Tri(t-butoxy)silanethiol 497(E)-1-Tri-n-butylstannyl-2-trimethylsilylethylene 499Trichloroiodosilane 500Triethoxysilane 501Triethylsilane 506Triethylsilyl Hydrotrioxide 5143-Triethylsilyloxy-1,4-pentadiene 515(a-Triethylsilyl)propionaldehyde Cyclohexylimine 516Triethylsilyl Trifluoromethanesulfonate 517Trimethylsilyl Trifluoromethanesulfonate 518Trifluoromethanesulfonic Acid, Chlorobis (1,1-Dimethylethyl)silyl Ester 537Trifluoromethyltrimethylsilane 539Triisopropylsilanethiol 546(Triisopropylsilyl)acetylene 550Triisopropylsilyl Chloride 554Triisopropylsilylethynyl Triflone 558Triisopropylsilyl Trifluoromethanesulfonate 559Trimethylsilylacetic Acid 562Trimethylsilylacetone 563Trimethylsilylacetonitrile 564Trimethylsilylacetylene 569(Trimethylsilyl)allene 580Trimethylsilylallyllithium 582(E)-1-Trimethylsilyl-1,3-butadiene 5853-Trimethylsilyl-3-buten-2-one 5869-[1-(Trimethylsilyl)-2(E)-butenyl] -9-borabicyclo[3.3.1]nonane 588Trimethylsilylcopper 589Trimethylsilyldiazomethane 590Trimethylsilyldiethylamine 5982-Trimethylsilyl-1,3-dithiane 6042-(Trimethylsilyl)ethanesulfonamide 609ß-Trimethylsilylethanesulfonyl Chloride 611[N-(2-(Trimethylsilyl)ethanesulfonyl)-imino]phenyliodane 6172-(Trimethylsilyl)ethanethiol 6182-(Trimethylsilyl)ethanol 6222-(Trimethylsilyl)ethoxycarbonylimidazole 6272-(Trimethylsilyl)ethoxymethyl Chloride 628[2-(Trimethylsilyl)ethoxymethyl]triphenylphosphonium Chloride 6332-(Trimethylsilyl)ethyl Chloroformate 6342-(Trimethylsilyl)ethyl 3-Nitro-1H-1,2,4-triazole-1-carboxylate 636(Trimethylsilyl)ethynylcopper(I) 637Trimethylsilyl Fluorosulfonyldifluoroacetate 638N-(Trimethylsilyl)imidazole 640Trimethylsilylketene 645Trimethylsilyllithium 650Trimethylsilyl Methanenitronate 6531-Trimethylsilyl-1-methoxyallene 656Trimethylsilylmethyl Azide 6571-[(Trimethylsilyl)methyl]-1H-benzotriazole 6582-Trimethylsilylmethyl-1,3-butadiene 6603-[(Trimethylsilyl)methyl]-3-butenoic Acid Methyl Ester 662Trimethylsilylmethyllithium 664Trimethylsilylmethylmagnesium Chloride 666Trimethylsilylmethylpotassium 6742-Trimethylsilylmethyl-2-propen-1-ol 6751-Trimethylsilyloxy-1,3-butadiene 6772-Trimethylsilyloxy-1,3-butadiene 6812-Trimethylsilyloxyfuran 684(Z)-2-(Trimethylsilyloxy)vinyllithium 6935-Trimethylsilyl-1,3-pentadiene 6952-(Trimethylsilyl)phenyl Triflate 697Trimethylsilylpotassium 7002-Trimethylsilyl-1,3-propanediol 7013-Trimethylsilyl-2-propen-1-yl Acetate 7033-Trimethylsilyl-1-propyne 7043-Trimethylsilyl-2-propynylcopper(I) 7112-(Trimethylsilyl)thiazole 712Trimethylsilyltributylstannane 7193-Trimethylsilyl-3-trimethylsilyloxy-1-propene 723(E)-1-Trimethylsilyl-2-trimethylstannylethylene 724(Trimethylsilyl)vinylketene 7251-(Trimethylsilyl)vinyllithium 726(E)-2-(Trimethylsilyl)vinyllithium 7291-(Trimethylsilyl)vinylmagnesium Bromide–Copper(I) Iodide 730Trimethyl{2-[(tributylstannyl)methyl]-2-propenyl}silane 731Triphenylsilane 733Tris(dimethylamino)sulfonium Difluorotrimethylsilicate 739Tris(trimethylsilyl)aluminum 745Tris(trimethylsilyl)methane 746Tris(trimethylsilyl)silane 747Vinyltrimethylsilane 755List of Contributors 763Reagent Formula Index 779Subject Index 785 ???