Rare Earth Elements

Fundamentals and Applications

Inbunden, Engelska, 2012

Av David A. Atwood, USA) Atwood, David A. (University of Kentucky, David A Atwood

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Lanthanides are of great importance for the electronic industries, this new book (from the EIBC Book Series) provides a comprehensive coverage of the basic chemistry, particularly inorganic chemistry, of the lanthanoid elements, those having a 4f shell of electrons. A chapter is describing the similarity of the Group 3 elements, Sc, Y, La, the group from which the lanthanoids originate and the group 13 elements, particularly aluminum, having similar properties. Inclusion of the group 3 and 13 elements demonstrates how the lanthanoid elements relate to other, more common, elements in the Periodic Table. Beginning chapters describe the occurrence and mineralogy of the elements, with a focus on structural features observed in compounds described in later chapters. The majority of the chapters is organized by the oxidation state of the elements, Ln(0), Ln(II), Ln(III), and Ln(IV). Within this organization the chapters are further distinguished by type of compound, inorganic (oxides and hydroxides, aqueous speciation, halides, alkoxides, amides and thiolates, and chelates) and organometallic. Concluding chapters deal with diverse and critically important applications of the lanthanoids in electronic and magnetic materials, and medical imaging.

Produktinformation

Utgivningsdatum2012-11-23
Mått222 x 287 x 36 mm
Vikt2 195 g
FormatInbunden
SpråkEngelska
SerieEIC Books
Antal sidor624
FörlagJohn Wiley & Sons Inc
ISBN9781119950974

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David Allan Atwood was born in 1965 in Urbana Illinois. At an early age David moved to Tuscaloosa Alabama where he grew up and ultimately attended college. After graduation from the University of Alabama he moved to Austin Texas to attend graduate school at the University of Texas with Richard Jones as his advisor. He graduated with his PhD (in Inorganic Chemistry) in the Spring of 1992 but stayed in Austin as a postdoctoral associate with Alan Cowley until his wife, Vicki Ossink Atwood, finished her PhD (also in Inorganic Chemistry). From UT he moved as an Assistant Professor to North Dakota State University as part of their new Center for Main Group Chemistry (of which he was co-director). In 1998 David Atwood joined the chemistry department at the University of Kentucky faculty as an Associate Professor. He now has over 160 publications, 10 patents, and serves on numerous editorial boards, including the Encyclopedia of Inorganic Chemistry, a 10 volume set published in Fall 2005. He is the founding editor and editor-in-chief of Main Group Chemistry. His research interests include detection and removal of heavy metal contaminants such as mercury, cadmium and lead, from the environment, the preparation of nanoparticulate metal oxides, prevention of aluminum alloy oxidation, and the synthesis of new Lewis acid compounds to effect new reactions, such as the breaking of phosphate esters bonds like those found in nerve gas agents and pesticides and the destruction of methyl-t-butyl ether (MTBE) a widespread water contaminant.

Contributors xiSeries Preface xvVolume Preface xviiGeology, Geochemistry, and Natural Abundances of the Rare Earth Elements 1Scott M. McLennan and Stuart Ross TaylorSustainability of Rare Earth Resources 21David A. AtwoodThe Electronic Structure of the Lanthanides 27Ana de Bettencourt-DiasVariable Valency 35Andrew W. G. PlattGroup Trends 43Andrew W. G. PlattSolvento Complexes of the Lanthanide Ions 55Simon A. Cotton and Jack M. HarrowfieldLanthanides in Living Systems 65Simon A. Cotton and Jack M. HarrowfieldLanthanides: Coordination Chemistry 73Simon A. Cotton and Jack M. HarrowfieldOrganometallic Chemistry Fundamental Properties 83Stephen T. LiddleLanthanides: “Comparison to 3d Metals” 105Simon A. CottonLuminescence 111Julien Andres and Anne-Sophie ChauvinLanthanides: Luminescence Applications 135Julien Andres and Anne-Sophie ChauvinMagnetism 153Bing-Wu Wang and Song GaoThe Divalent State in Solid Rare Earth Metal Halides 161Gerd MeyerLanthanide Halides 175Timothy J. Boyle and Leigh Anna M. SteeleLanthanide Oxide/Hydroxide Complexes 183Zhiping ZhengLanthanide Alkoxides 197Timothy J. Boyle and Leigh Anna M. SteeleRare Earth Siloxides 205Clemens Krempner and Brian McNerneyThiolates, Selenolates, and Tellurolates 215John G. BrennanCarboxylate 225Jia-sheng Lu and Ruiyao WangLanthanide Complexes with Amino Acids 237Zhiping Zhengβ-Diketonate 249Ke-Zhi WangRare Earth Borides, Carbides and Nitrides 263Takao MoriLanthanide Complexes with Multidentate Ligands 281Xiaoping Yang, Richard A. Jones and Wai-Kwok WongAlkyl 299Simon A. CottonAryls 303Simon A. CottonTrivalent Chemistry: Cyclopentadienyl 307Roman A. KresinskiTetravalent Chemistry: Inorganic 313Farid M. A. Sroor and Frank T. EdelmannTetravelent Chemistry: Organometallic 321Farid M. A. Sroor and Frank T. EdelmannMolecular Magnetic Materials 335Bing-Wu Wang and Song GaoNear-Infrared Materials 347Lining Sun and Liyi ShiSuperconducting Materials 371Antonio J. Dos santos-Garcia, Miguel Á. Alario-Franco and Regino Sáez-PucheMetal-Organic Frameworks 385John Hamilton Walrod II and David A. AtwoodUpconversion Nanoparticles for Bioimaging Applications 389Jiefu Jin and Wing-Tak WongOxide and Sulfide Nanomaterials 405Takuya TsuzukiRare Earth Metal Cluster Complexes 415Gerd MeyerOrganic Synthesis 437Yuichiro Mori and Shũ KobayashiHomogeneous Catalysis 459Yingming Yao and Kun NieHeterogeneous Catalysis 475John Hamilton Walrod II and David A. AtwoodSupramolecular Chemistry: from Sensors and Imaging Agents to Functional Mononuclear and Polynuclear Self-Assembly Lanthanide Complexes 481Jonathan A. Kitchen and Thorfinnur GunnlaugssonEndohedral Fullerenes 495Daniel L. Burriss and David A. AtwoodLanthanide Shift Reagents 501Carlos F. G. C. GeraldesLanthanides: Magnetic Resonance Imaging 521Sophie Laurent, Luce Vander Elst, Sebastien Boutry and Robert N. MullerLuminescent Bioprobes 535Anne-Sophie ChauvinSensors for Lanthanides and Actinides 561Gabriela I. Vargas-Zúñiga and Jonathan L. SesslerIndex 575

“In conclusion this is a valuable book, spanning the under-graduate / postgraduate divide, which should find a place particularly in the collections of those who teach lanthanide chemistry and new researchers to the field who want to discover the remarkable scope of modern lanthanide chemistry and its exciting applications. One could not expect much more in a single volume.” (Applied Organometal Chemistry, 1 May 2013)