Polymeric Corrosion Inhibitors for Greening the Chemical and Petrochemical Industry

Mohammad A. Jafar Mazumder serves as an Associate Professor of Chemistry at KFUPM, Saudi Arabia.Mumtaz A. Quraishi is a Chair Professor at the Center of Research Excellence in Corrosion at King Fahd University of Petroleum and Minerals, Saudi Arabia.Amir Al-Ahmed is working as a Research Scientist-II (Associate Professor) in the Center of Research Excellence in Renewable Energy (CoRE-RE) at King Fahd University of Petroleum & Minerals (KFUPM), Saudi Arabia.

• Preface xvAcknowledgments xviiAbout the Editors xix1 Green Polymeric Corrosion Inhibitors: Design, Synthesis, and Characterization 1Dheeraj S. Chauhan, Mumtaz A. Quraishi, Hussein Al-Qahtani, and Mohammad A. Jafar Mazumder1.1 Introduction 11.2 Corrosion and Its Economic Significance 21.3 Corrosion Inhibitors 21.4 Polysaccharides as Corrosion Inhibitors 41.5 Proteins and Polyamino Acids as Corrosion Inhibitors 71.6 Chemically Modified Biopolymers as Corrosion Inhibitors 101.7 Biopolymer Nanoparticles as Corrosion Inhibitors 131.8 Biopolymer Composites as Corrosion Inhibitors 131.9 Adsorption and Protection Mechanism of Biopolymers on the Metal Surface 141.10 Conclusions and Prospects 162 Natural Polymers and Their Derivatives as Corrosion Inhibitors for the Oil and Gas Industry 23Ali F.S.A. Rahiman, Menaka Ramanathan, and Sethumanickam Subhashini2.1 Introduction 232.2 Reliable Methods for the Study of Polymeric Corrosion Inhibitors 242.3 Natural Polymeric Corrosion Inhibitors 262.4 Mechanism for Natural Polymeric Corrosion Inhibition 412.5 Conclusion and Outtake for FutureWork 423 Current Applications of Carbohydrates as Green Corrosion Inhibitors for the Oil and Gas Industry 55Ruby Aslam, Mohammad Mobin, Saman Zehra, and Jeenat Aslam3.1 Introduction 553.2 Carbohydrate Polymers: A Sustainable Alternatives 573.3 Conclusion 734 Poly(Amino Acid) Corrosion Inhibitors 79Brahim El Ibrahimi and Nada K. Sebbar4.1 Introduction 794.2 Poly(Amino Acid) Homopolymers as Corrosion Inhibitors 814.3 Modified Poly(Amino Acid) and Poly(Amino Acid) Copolymers as Corrosion Inhibitors 844.4 Poly(Amino Acid) Composite Polymers as Corrosion Inhibitors 894.5 Conclusion 925 Water-Soluble Polymeric Corrosion Inhibitors 97Lipiar K.M.O. Goni, Mohammad A. Jafar Mazumder, Shaikh A. Ali, and Dheeraj S. Chauhan5.1 Introduction 975.2 Polymers asWater-Soluble Corrosion Inhibitors 985.3 Industrial Applications ofWater-Soluble Polymeric Corrosion Inhibitors 1135.4 Conclusions 1166 High-Temperature Polymeric Corrosion Inhibitors 125Jiyaul Haque, Mumtaz A. Quraishi, and Wan M.N.B. Wan Nik6.1 Introduction 1256.2 Polymer as Corrosion Inhibitor for High-Temperature Oil-Well Acidization 1266.3 Polymer as Corrosion Inhibitor for High-Temperature Sour and Sweet Environment 1316.4 Polymer as Corrosion Inhibitor for High-Temperature Naphthenic Acids Environment 1336.5 Computational Studies of Polymeric Corrosion Inhibitors 1346.6 Conclusions and Outlook 1387 Polyurethane Corrosion Inhibitor 143Mohammad M. Rahman7.1 Introduction 1437.2 Polyurethane (PU) 1447.3 Polymer as an Inhibitor 1477.4 PU as Corrosion Inhibitor (PUCI) 1487.5 Mechanism of PUCI Inhibition 1547.6 Conclusions and Perspectives 1558 Dual-Purpose Kinetic Hydrate and Corrosion Inhibitors 161Muhammad I. Ulhaq8.1 Introduction 1618.2 Corrosion Inhibitors (CIs) 1648.3 Kinetic Hydrate Inhibitors (KHIs) 1678.4 Dual-Purpose Chemicals 1708.5 Dual-Purpose Corrosion Inhibitor and KHIs (GHCIs) 1708.6 Conclusion and Future Prospects 1809 Polymers as Corrosion Inhibitors for Sweet Environment 193Dheeraj S. Chauhan, Vandana Srivastava, Yuanhua Lin, and Mumtaz A. Quraishi9.1 Introduction 1939.2 An Overview of Corrosion 1949.3 Sweet Corrosion 1959.4 Polymers as Sweet CI 2059.5 Computational Modeling of Polymeric Inhibitors for Sweet Corrosion 2129.6 Mechanism of Adsorption and Inhibition 2149.7 Conclusions and Prospects 21510 Green Polymeric Inhibitors for Corrosion of Metals in Alkaline Media 221Refat M. Hassan (El-Moushy)10.1 Definitions of Corrosion 22110.2 Main Reasons for Metals Corrosion 22210.3 Theories of Corrosion 22210.4 General Types of Corrosions 22410.5 Corrosion Reactions of Al in Alkaline Media 22910.6 Techniques for Prevention and Protection ofMetals from Corrosion 23010.7 Applied Methodologies for Measurements of Corrosion Rates 23510.8 Factors Affecting the Corrosion Process 23610.9 Conclusion 24611 Polymeric Corrosion Inhibitors for Acid Media 257Nurudeen A. Odewunmi, Mohammad A. Jafar Mazumder, and Shaikh A. Ali11.1 Background 25711.2 Outward and Inward Acid Corrosion 25811.3 Organic and Inorganic Corrosion Inhibitor in Acid Media 25911.4 Natural Polymeric Materials 26211.5 Essential Oils 26211.6 Carbohydrates (CHO) 26311.7 Natural Proteins 27211.8 Synthetic Polymeric Materials 27511.9 Conclusion 28912 Polymeric Corrosion Inhibitors for Microbiologically Influenced Corrosion 305Chaitanya Kumar, Mohan Yama, and Jaya Rawat12.1 Introduction to Microbiologically Influenced Corrosion (MIC) 30512.2 Microbes in MIC 30612.3 Biofilms 30712.4 MIC Issues in Industry: Oil and Gas 30912.5 Corrosion Inhibitors for MIC 31012.6 Polymeric Corrosion Inhibitors 31212.7 Conclusions 31713 Smart Polymers Coating for Upstream Oil and Gas Industry to Slow Down the Corrosion 331Rabia Nazar, Umer Mehmood, Hassan Ahmed, Aimen Imran, and Syed A. Raza13.1 Introduction 33113.2 Mechanism of Corrosion 33413.3 Kinds of Corrosion in Industry 33713.4 Conventional Corrosion Prevention Methods 34113.5 Smart Coatings 34313.6 Conclusion 34914 Surface Characterization Techniques in Corrosion Inhibition Research 353Ambrish Singh, Kashif R. Ansari, Shivani Singh, Mumtaz A. Quraishi, and Yuanhua Lin14.1 Introduction 35314.2 Method ofWeight Loss 35414.3 Parameters of Adsorption 35714.4 Electrochemical Techniques 36014.5 Surface Analytical Techniques 36714.6 Conclusion 37815 Guidelines for Designing Corrosion Inhibitors for Oil and Gas Production 383Nayef M. Alanazi and Muhammad I. Ulhaq15.1 Introduction 38315.2 Classification of Corrosion 38415.3 Corrosion Inhibitors 38515.4 Corrosion Inhibitor Management 39315.5 Safety on Designing Corrosion Inhibitor 39915.6 Conclusions 399Acknowledgment 400List of Abbreviations 400References 400Index 407