Jemistry Daniels, the beautiful, intelligent, six-figures-a-year high school principal, suffered through one bad relationship after another. No wonder she adopted the "friends with benefits" mentality when it came to men. For Jemistry, there was to be no "catching feelings." Her biggest mistake would be to open her heart again. When Dr. Tevin Harris meets Jemistry at a poetry reading in a café, he knows from her confessional writing that her past with men has been difficult. The prominent vascular surgeon, who has been only casually dating for years, is attracted to the embittered Jemistry nonetheless. With a little persistence, Tevin convinces Jemistry to go out with him. She has baggage, but so does he. What about his divorce? Despite their respective pasts, Jemistry and Tevin's chemistry is right and the relationship takes off, but not without bumps in the road. When Jemistry encounters her new beau in a compromising position with her bisexual best friend, what follows is an intense, sensuous, and unforgettable drama with surprises around every turn.