Organoderivatives of Rare Earth Elements

Inbunden, Engelska, 1995

AvM.N. Bochkarev,Lev N. Zakharov,Galina S. Kalinina,M. N. Bochkarev,Mikhail Bochkarev

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This volume contains a description of the synthesis, structure, physicochemical and catalytic properties of organometallic complexes of yttrium, scandium, lanthanum and lanthanoids. Along with the true organometallics, the alcoholates, thiolates, amides and similar classes of compounds are considered. The last section of the book deals with practical applications of organic derivatives of rare earth elements. The book contains a large number of tables and illustrations giving physicochemical, spectral and structural characteristics or organoderivatives of lanthanoids. The comprehensive data presented obviate the need to refer to original publications.

Produktinformation

Utgivningsdatum1995-07-31
Mått155 x 235 x 34 mm
Vikt975 g
FormatInbunden
SpråkEngelska
SerieTopics in F-Element Chemistry
Antal sidor533
Upplaga1995
FörlagKluwer Academic Publishers
ISBN9780792331537

Tillhör följande kategorier

I. ?-Alkyl and ?-aryl complexes.- I.1. Di-and trialkyl(aryl)lanthanoids.- 1.2. Complexes of ate-type.- I.3. Compounds with cyclopentadienyl and ?1-bonded ligands.- I.4. Compounds with cyclooctatetraenyl and ?1-bonded ligands.- I.5. Ylide and zwitterionic complexes.- References.- II ?3-Allyl and similar complexes.- II.1. Synthesis and properties.- 11.2. Spectroscopic data.- References.- III Cyclopentadienyl derivatives.- III.1. Dicyclopentadienyl complexes.- I11.2. Tricyclopentadienyl complexes.- III.3. Complexes with coordinate bonded ligands.- 111.4. Halides and related compounds of REM cyclopentadienides.- III.5. Heterobimetallic complexes of ate-type.- References.- IV Complexes with the cyclic polyene ligands.- IV.1. Indenyl complexes.- IV.2. Fluorenyl complexes.- IV.3. Cycloheptatrienyl complexes.- IV.4. Cyclooctatetraenyl complexes.- IV. 5. Arene complexes of lanthanoids.- References.- V Organohydrides of lanthanoids.- V.1. Synthesis.- V.2. Structure.- V.3. Properties.- V.4. Spectral data.- References.- VI Compounds with a Ln-N bond.- VI.1. Synthesis.- VI.2. Structure.- VI.3. Properties.- References.- VII Compounds with Ln-P and Ln-As bonds.- VII.1. Phosphorus derivatives.- VII.2. Arsenic derivatives.- References.- VIII Compounds with a Ln-O bond.- VIII. 1. Alkoxides of Ln(OR)3 type.- VIII.2. Halide/alkoxides of REM and other derivatives of the Ln(OR)3-xYxtype.- VIII.3. Alkoxides, oxides and hydroxides of cyclopentadienyllanthanoids.- VIII.4. Bimetallic alkoxides.- References.- IX The compounds with a lanthanoid-chalcogen bond.- IX.1. Synthesis and properties.- IX.2. Structure.- References.- X Compounds with lanthanoid-metal bonds.- X.1. The derivatives of nontransition metals.- X.2. Complexes of REM with carbonyls and nitrosyls oftransition metals.-References.- XIComplexes of Ce(IV).- References.- XII Miscellaneous compounds.- XII.1. Carbonyls.- XII.2. Graphite intercalates.- XII.3. Phthalocyanines and porphyrins.- XII.4. Complexes with other nitrogen containing ligands.- XII.5. Products of gas phase reactions of Ln+ with hydrocarbons.- XII.6. Clusters.- References.- XIII Applications of organolanthanoids.- XIII.1. Catalysis of polymerization.- XIII.2. Catalysts and reagents for reductionand oxidation processes.- XIII.3. Miscellaneous applications of REM compounds.- References.