Organic Syntheses, Volume 93

Huw M. L. Davies, PhD, joined the Emory University faculty in 2008 as the Asa Griggs Candler Professor of Organic Chemistry. Prior to Emory, he held the positions of UB Distinguished Professor and Larkin Professor of Organic Chemistry at the University at Buffalo, the State University of New York. Dr. Davies received his BSc degree from University College in Cardiff, Wales and his PhD from the University of East Anglia. He completed his post-doctoral training at Princeton University.

• DIBALH-Mediated Reductive Ring-Expansion Reaction of Cyclic Ketoxime 1Taku Imaizumi, Kentaro Okano, and Hidetoshi TokuyamaPreparation of 2-(2-(Dicyclohexylphosphino)phenyl)-1-methyl-1H-indole (CM-phos) 14Shun Man Wong, On Ying Yuen, Pui Ying Choy, Chau Ming So, and Fuk Yee KwongSynthesis of 5-(Hydroxymethyl)furfural (HMF) 29Svilen P. Simeonov, Jaime A. S. Coelho, and Carlos A. M. AfonsoErratum for: Titanium-Mediated Addition of Silyl Dienol Ethers to Electrophilic Glycine: 4 Ketopipecolic Acid Hydrochloride 37Clarisse Mühlemann, Peter Hartmann, and Jean-Pierre ObrechtNickel-Catalyzed Synthesis of Ketones from Alkyl Halides and Acid Chlorides: Preparation of Ethyl 4-Oxododecanoate 50Alexander C. Wotal, Donald C. Batesky, and Daniel J. WeixTrichloroboron-promoted Deprotection of Phenolic Benzyl Ether UsingPentamethylbenzene as a Non Lewis-Basic Cation Scavenger 63Shun Okaya, Keiichiro Okuyama, Kentaro Okano, and Hidetoshi TokuyamaEnantioselective Synthesis of α,α-Disubstituted Lactones via a Chiral Brønsted Acid-Catalyzed Intramolecular Cyclization 75Jennifer E. Wilent, Ghassan Qabaja, and Kimberly S. PetersenEnantioselective Synthesis of α-Bromonitroalkanes for Umpolung Amide Synthesis: Preparation of tert-Butyl ((1R)-1-(4-(benzyloxy)phenyl)-2-bromo-2-nitroethyl)carbamate 88Victoria T. Lim, Sergey V. Tsukanov, Amanda B. Stephens, and Jeffrey N. JohnstonSynthesis of 1-Bromopyrene and 1-Pyrenecarbaldehyde 100Matthias Schulze, Alexander Scherer, Colin Diner, and Rik R. TykwinskiIntermolecular [2+2] Cycloaddition of Alkynes with Alkenes Catalyzed by Gold(I) 115M. Elena de Orbe and Antonio M. EchavarrenPhotochemical Benzannulation of N-Phosphoryl Ynamides and α-Diazo Ketones in Continuous Flow 127John M. Read, Yu-Pu Wang, and Rick L. DanheiserTrifluoromethylation of Aryl Iodides Catalyzed by the Copper(I)-Phen Complex 147Naoto Shimizu, Hideaki Kondo, Masahiro Oishi, Kenichi Fujikawa, Kazuki Komoda, and Hideki AmiiCopper-catalyzed Cyanation of Alkenyl Iodides 163Antoine Nitelet, Sara Zahim, Cédric Theunissen, Alexandre Pradal, and Gwilherm EvanoVisible Light Photocatalysis of Radical Cation Diels–Alder Cycloadditions: Preparation of Tris(2,2’-bipyrazyl) Ruthenium(II) Bis(tetrakis(3,5-bis(trifluoromethyl)phenyl)borate) 178Shane D. Lies, Shishi Lin, and Tehshik P. YoonPreparation of Methyl 1,2,3,4-tetra-O-acetyl-β-D-glucopyranuronate 200Aisling Ní Cheallaigh, Garrett T. Potter, John M. Gardiner, and Gavin J. MillerPreparation of 1,5-Dioxaspiro[5.5]undecan-3-one 210Robert A. Craig, II, Russell C. Smith, Beau P. Pritchett, Benzi I. Estipona, and Brian M. StoltzOxyboration: Synthesis of Borylated Benzofurans 228Darius J. Faizi, Nicole A. Nava, Mohammad Al-Amin, and Suzanne A. BlumSynthesis of 1-Iodopropyne 245Samuel G. Bartko, James Deng, and Rick L. DanheiserPotassium tert-Butoxide–Catalyzed Dehydrogenative Cross-Coupling of Heteroarenes with Hydrosilanes 263Anton A. Toutov, Wen-Bo Liu, Brian M. Stoltz, and Robert H. GrubbsSynthesis of α-Carboline 272Linli He, Shawn P. Allwein, Benjamin J. Dugan, Kyle W. Knouse, Gregory R. Ott, and Craig A. ZificsakSynthesis of Methyl 1-Formylcyclopropanecarboxylate utilizing Ti-Claisen Condensation 286Yuichiro Ashida, Satomi Kajimoto, Hidefumi Nakatsuji, and Yoo TanabeNickel-Catalyzed Suzuki–Miyaura Coupling in t-Amyl Alcohol for the Preparation of 5-(Furan-3-yl)pyrimidine 306Liana Hie and Neil K. GargPreparation of (S)-Nonafluorobutanesulfinamide 319Apiwat Wangweerawong, Scott Kolmar, and Jonathan A. EllmanPreparation of 1-Methylimidazole-N-oxide (NMI-O) 331James I. Murray and Alan C. SpiveyPalladium-Catalyzed Direct Amination of Allylic Alcohols at Room Temperature 341Bao Gao, Lixin Li, Guoying Zhang, and Hanmin HuangPreparation of 1,1-Difluoroallenes by Difluorovinylidenation of Carbonyl Compounds 352Kohei Fuchibe, Masashi Abe, Ken Oh, and Junji IchikawaRhodium-Catalyzed Addition of Carboxylic Acids to Terminal Alkynes towards Z-Enol Esters 367Stephanie Ganss, Julia Pedroni, Alexandre Lumbroso, Günther Leonhardt-Lutterbeck, Antje Meißner, Siping Wei, Hans-Joachim Drexler, Detlef Heller, and Bernhard BreitCopper-Catalyzed Semi-Reduction of Alkynes 385Nick Cox, Hester Dang, Aaron M. Whittaker, and Gojko LalicSynthesis of Cyclobutanes by Lewis Acid-Promoted Ketene-Alkene [2+2] Cycloadditions 401Christopher M. Rasik, Eleni M. Salyers, and M. Kevin BrownSynthesis of 2,2-Dichloroimidazolidine-4,5-diones and their Application in Chlorodehydroxylation 413David Schilter and Christopher W. Bielawski