Organic Spectroscopy Workbook

TOM FORREST, Department of Chemistry, Dalhousie University, Canada JEAN-PIERRE RABINE, Centre de Développement Informatique Enseignement Chimie, Université de Nice Sophia-Antipolis, France MICHEL ROUILLARD, Centre de Développement Informatique Enseignement Chimie, Université de Nice Sophia-Antipolis, France

• Preface viiAcknowledgements ixHow to Use this Workbook 1Preliminary Observations 2Centres of Unsaturation 8Exercises 1–100 10Infrared Data 210IR Frequencies: Display of Infrared Database by Frequency 210IR Groups: Display of Infrared Database by Functional Group 2161H NMR Data 221General Tables of Functional Groups 221Comparison of δ of Alkyl Groups Bearing a Substituent in α or β Position 225Alkyl Groups with an α Substituent 226Alkyl Groups with a β Substituent 226Tables of δ for −CH2− Doubly Substituted in α Position 227Tables of δ for Aromatics 229Coupling Constants 23013C NMR Data 233General Ranges for CH3−, −CH2−, >CH−. . . 233Chemical Shift Ranges for Functional Groups 234Chemical Shift Estimations 234Mass Spectrometry Data 240Main Fragments Observed 240Atomic Masses 242Isotopic Abundances in % 243Internet Resources 254Glossary of Terms Used in the Exercises 255Answers 257Index 261