SCOTT E. DENMARK is the Reynold C. Fuson Professor of Chemistry at the University of Illinois at Urbana-Champaign. He has pioneered the concept of chiral Lewis base activation of Lewis acids for catalysis in main group synthetic organic chemistry. His group has also developed palladium-catalyzed cross-couplings with organofunctional silicon compounds. He has won a number of honors including the Pedler and Robert Robinson Medals, the Aldrich Award for Creative Work in Synthetic Organic Chemistry and the Prelog Medal. He was a founding editor of the Encyclopedia of Reagents for Organic Synthesis and served as Editor in Chief of Organic Reactions from 2008 to 2018. He is a member of the American Academy of Arts and Sciences and the National Academy of Sciences.

• 1. The Negishi Cross-Coupling Reaction 1Colin Diner and Michael G. Organ2. Generation and Trapping of Functionalized Aryl- and Heteroarylmagnesium and -Zinc Compounds 63Ferdinand H. Lutter, Maximilian S. Hofmayer, Jeffrey M. Hammann, Vladimir Malakhov, and Paul Knochel3. Copper-Catalyzed, Enantioselective Hydrofunctionalization of Alkenes 121Haoxuan Wang and Stephen L. Buchwald4. The Catalytic, Enantioselective Favorskii Reaction: in Situ Formation of Metal Alkynylides and Their Additions to Aldehydes 207Yeshua Sempere and Erick M. Carreira5. Enantioselective Lithiation–Substitution of Nitrogen-Containing Heterocycles 255Kevin Kasten, Nico Seling, and Peter O’Brien6. Catalytic, Enantioselective, Transfer Hydrogenation 329Masahiro Yoshimura and Masato Kitamura7. Hydrofunctionalization of Alkenes by Hydrogen-Atom Transfer 383Ryan A. Shenvi, Jeishla L. M. Matos, and Samantha A. Green8. Carbon–Carbon Bond Formation by Metallaphotoredox Catalysis 471Eric D. Nacsa and David W. C. MacMillan9. Suzuki–Miyaura Cross-Coupling 547Alexander B. Pagett and Guy C. Lloyd-Jones10. ortho-Directed C–H Alkylation of Substituted Benzenes 621Yusuke Ano and Naoto Chatani 11. Catalytic, Enantioselective, C–H Functionalization to Form Carbon–Carbon Bonds 671Qing-Feng Wu, Gang Chen, Jian He, and Jin-Quan Yu12. Catalytic, Enantioselective Fluorination Reactions 749Richard T. Thornbury and F. Dean Toste13. Catalyst-Controlled Glycosylation 801Samuel M. Levi and Eric N. Jacobsen14. Palladium-Catalyzed Amination of Aryl Halides 853John F. Hartwig, Kevin H. Shaughnessy, Shashank Shekhar, and Rebecca A. Green15. Catalytic, Enantioselective, Copper–Boryl Additions to Alkenes 959Amir H. Hoveyda, Ming Joo Koh, Kyunga Lee, and Jaehee LeeCumulative Chapter Titles by Volume 1057Author Index, Volumes 1–100 1075Chapter and Topic Index, Volumes 1–100 1083

SCOTT E. DENMARK is the Reynold C. Fuson Professor of Chemistry at the University of Illinois at Urbana-Champaign. He has pioneered the concept of chiral Lewis base activation of Lewis acids for catalysis in main group synthetic organic chemistry. His group has also developed palladium-catalyzed cross-couplings with organofunctional silicon compounds. He has won a number of honors including the Pedler and Robert Robinson Medals, the Aldrich Award for Creative Work in Synthetic Organic Chemistry and the Prelog Medal. He was a founding editor of the Encyclopedia of Reagents for Organic Synthesis and served as Editor in Chief of Organic Reactions from 2008 to 2018. He is a member of the American Academy of Arts and Sciences and the National Academy of Sciences.

• 1. The Negishi Cross-Coupling Reaction 1Colin Diner and Michael G. Organ2. Generation and Trapping of Functionalized Aryl- and Heteroarylmagnesium and -Zinc Compounds 63Ferdinand H. Lutter, Maximilian S. Hofmayer, Jeffrey M. Hammann, Vladimir Malakhov, and Paul Knochel3. Copper-Catalyzed, Enantioselective Hydrofunctionalization of Alkenes 121Haoxuan Wang and Stephen L. Buchwald4. The Catalytic, Enantioselective Favorskii Reaction: in Situ Formation of Metal Alkynylides and Their Additions to Aldehydes 207Yeshua Sempere and Erick M. Carreira5. Enantioselective Lithiation–Substitution of Nitrogen-Containing Heterocycles 255Kevin Kasten, Nico Seling, and Peter O’Brien6. Catalytic, Enantioselective, Transfer Hydrogenation 329Masahiro Yoshimura and Masato Kitamura7. Hydrofunctionalization of Alkenes by Hydrogen-Atom Transfer 383Ryan A. Shenvi, Jeishla L. M. Matos, and Samantha A. Green8. Carbon–Carbon Bond Formation by Metallaphotoredox Catalysis 471Eric D. Nacsa and David W. C. MacMillan9. Suzuki–Miyaura Cross-Coupling 547Alexander B. Pagett and Guy C. Lloyd-Jones10. ortho-Directed C–H Alkylation of Substituted Benzenes 621Yusuke Ano and Naoto Chatani 11. Catalytic, Enantioselective, C–H Functionalization to Form Carbon–Carbon Bonds 671Qing-Feng Wu, Gang Chen, Jian He, and Jin-Quan Yu12. Catalytic, Enantioselective Fluorination Reactions 749Richard T. Thornbury and F. Dean Toste13. Catalyst-Controlled Glycosylation 801Samuel M. Levi and Eric N. Jacobsen14. Palladium-Catalyzed Amination of Aryl Halides 853John F. Hartwig, Kevin H. Shaughnessy, Shashank Shekhar, and Rebecca A. Green15. Catalytic, Enantioselective, Copper–Boryl Additions to Alkenes 959Amir H. Hoveyda, Ming Joo Koh, Kyunga Lee, and Jaehee LeeCumulative Chapter Titles by Volume 1057Author Index, Volumes 1–100 1075Chapter and Topic Index, Volumes 1–100 1083

SCOTT E. DENMARK is the Reynold C. Fuson Professor of Chemistry at the University of Illinois at Urbana-Champaign. He has pioneered the concept of chiral Lewis base activation of Lewis acids for catalysis in main group synthetic organic chemistry. His group has also developed palladium-catalyzed cross-couplings with organofunctional silicon compounds. He has won a number of honors including the Pedler and Robert Robinson Medals, the Aldrich Award for Creative Work in Synthetic Organic Chemistry and the Prelog Medal. He was a founding editor of the Encyclopedia of Reagents for Organic Synthesis and served as Editor in Chief of Organic Reactions from 2008 to 2018. He is a member of the American Academy of Arts and Sciences and the National Academy of Sciences.

• 1. The Negishi Cross-Coupling Reaction 1Colin Diner and Michael G. Organ2. Generation and Trapping of Functionalized Aryl- and Heteroarylmagnesium and -Zinc Compounds 63Ferdinand H. Lutter, Maximilian S. Hofmayer, Jeffrey M. Hammann, Vladimir Malakhov, and Paul Knochel3. Copper-Catalyzed, Enantioselective Hydrofunctionalization of Alkenes 121Haoxuan Wang and Stephen L. Buchwald4. The Catalytic, Enantioselective Favorskii Reaction: in Situ Formation of Metal Alkynylides and Their Additions to Aldehydes 207Yeshua Sempere and Erick M. Carreira5. Enantioselective Lithiation–Substitution of Nitrogen-Containing Heterocycles 255Kevin Kasten, Nico Seling, and Peter O’Brien6. Catalytic, Enantioselective, Transfer Hydrogenation 329Masahiro Yoshimura and Masato Kitamura7. Hydrofunctionalization of Alkenes by Hydrogen-Atom Transfer 383Ryan A. Shenvi, Jeishla L. M. Matos, and Samantha A. Green8. Carbon–Carbon Bond Formation by Metallaphotoredox Catalysis 471Eric D. Nacsa and David W. C. MacMillan9. Suzuki–Miyaura Cross-Coupling 547Alexander B. Pagett and Guy C. Lloyd-Jones10. ortho-Directed C–H Alkylation of Substituted Benzenes 621Yusuke Ano and Naoto Chatani 11. Catalytic, Enantioselective, C–H Functionalization to Form Carbon–Carbon Bonds 671Qing-Feng Wu, Gang Chen, Jian He, and Jin-Quan Yu12. Catalytic, Enantioselective Fluorination Reactions 749Richard T. Thornbury and F. Dean Toste13. Catalyst-Controlled Glycosylation 801Samuel M. Levi and Eric N. Jacobsen14. Palladium-Catalyzed Amination of Aryl Halides 853John F. Hartwig, Kevin H. Shaughnessy, Shashank Shekhar, and Rebecca A. Green15. Catalytic, Enantioselective, Copper–Boryl Additions to Alkenes 959Amir H. Hoveyda, Ming Joo Koh, Kyunga Lee, and Jaehee LeeCumulative Chapter Titles by Volume 1057Author Index, Volumes 1–100 1075Chapter and Topic Index, Volumes 1–100 1083