Esterification

Junzo Otera was born in Hyogo, Japan in 1943. He obtained his PhD degree in 1971 from Osaka University, and then became a research chemist in Central Research Laboratories of Juraray Co. In 1979, he moved to Okayama University of Science as Associate Professor and has been Full Professor there since 1986. In the meantime, he served as a visiting professor in many universities in Japan, USA, France, Spain and Australia. his research interests are focused on Lewis acid catalysts, heteroatom chemistry, fluorous chemistry, and green process chemistry. Joji Nishikido received his M.Sc. from Kyushu University in 1970 and joined Asahi Chemical Industrial Co., Ltd. in the same year. He moved to The Noguchi Institute in 1997 and returned to Asahi Kasei Corporation as chief chemist in 2004. His research interests are in the area of synthetic organic chemistry, Lewis acid catalysts, and green chemistry.

• PrefaceIntroduction PART 1: Methodology REACTION OF ALCOHOLS WITH CARBOXYLIC ACIDS AND THEIR DERIVATIVESReaction with Carboxylic AcidsReaction with Esters: TransesterificationReaction with Acid AnhydridesReaction with Acid Halides and Other Acyl DerivativesUSE OF TIN AND OTHER METAL ALKOXIDESCONVERSION OF CARBOCYLIC ACIDS TO ESTERS WITHOUT USE OF ALCOHOLSReaction with DiazomethaneReaction with Alkyl HalidesReaction with Other ElectrophilesESTER-INTERCHANGE REACTION PART 2: Synthetic Applications KINETIC RESOLUTIONEnzymatic ResolutionNonenzymatic ResolutionDynamic Kinetic ResolutionParallel Kinetic ResolutionASYMMETRIC DESYMMETRIZATIONMISCELLANEOUS TOPICSSelective EsterificationUse of Theoretical Amounts of ReactantsNew Reaction MediaNew TechnologiesApplications to Natural Products SynthesisINDUSTRIAL USESEthyl AcetateAcrylic EstersPolyestersOils and FatsBiodiesel FuelAmino Acid EstersMacrolidesFlavoring Agents and FragrancesPyrethroids

"...Otera's book does a good job, concisely covering the esterification methodology literature from 1990 to 1999, and that survey will be useful to synthetic organic chemists..." Angewandte Chemie IE, Vol. 43