Energetics of Organometallic Species

Proceedings of the NATO Advanced Study Institute, Curia, Portugal, September 3-13, 1991

Inbunden, Engelska, 1992

Av Simoes J a Martinho, J. A. Martinho Simoes, Josi A. Martinho Simues, José A. Martinho Simões, Josi A Martinho Simues, Jose A Martinho Simc5es, Josa(c) A Martinho Simaes

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Why has the energetics of organometallic species become an area of recognized importance? What methods are available to obtain information on reaction enthalpies and bond "strengths"? What other methods are likely to be used in the future? Is the present thermochemical data bank satisfactory for our needs? How accurately can we estimate the energetics of organometallic reactions? Can theory offer reliable help? Which are the main problems to be tackled by the experimentalist? These are some of the questions addressed in this text, which contains contributions by many of the leading groups in the are or organometallic thermochemistry.

Produktinformation

Utgivningsdatum1992-04-30
Mått160 x 230 x 31 mm
Vikt852 g
FormatInbunden
SpråkEngelska
SerieNATO Science Series: C: Mathematical & Physical Sciences
Antal sidor448
FörlagKluwer Academic Publishers
ISBN9780792317074

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Historical perspective of organometallic thermochemistry; combustion calorimetry of organometallic compounds; organo-f-element thermochemistry, implications for reactivity and bonding from metal-ligand bonding energetics; the role of bond energies in hydrocarbon activation by transition metal centers; Rh-C bond dissociation enthalpies for organometallic derivatives of rhodium pophyrins; solution thermochemistry of organometallic compounds using photoacoustic calorimetry - enthalpies of liquid exchange, metal-ligand bonds and metal-solvent interactions; electrochemistry of some organic and organometallic radicals and their application in thermochemical cycles; derivative cyclic voltammetry - applications in the investigation of the energetics of organometallic electrode reactions; the use of calometric and sublimation techniques to study bond properties in organometallic compounds; estimations enthalpies of sublimation of hydrocarbons; derivation of thermodynamic quantities from kinetic measurments in gas phase silane chemistry; bond enthalpy transferability - is it achievable?; estimates of thermochemical data for organometallic compounds; bonding and solvation energetics for organometallic gas-phase molecules and ions - experimental approaches and thermodynamic insights; gas-phase activities of transition-metal carbonyl and trifluorophosphine hydrides; bond strengths in transition metal carbonyl anions; fundamental gas-phase studies of the mechanism and thermochemistry of organometallic species; a guide to density functional theory and its practical applications to the energetics of organometallic species; theoretical models for organometallic reactions.