The two-volume set LNAI 13495 and LNAI 13496, constitute the refereed post-workshop proceedings of the 23rd Chinese Lexical Semantics Workshop, CLSW 2022, held as a virtual event, during May 14-15, 2022.In total the two-volume set includes 39 full papers and 19 short papers which were carefully reviewed and selected from 214 submissions. They are organized in the following topical sections: lexical semantics; corpus linguistics; general linguistics, lexical resources; computational linguistics, applications of natural language processing.