Del i serien Patai's Chemistry of Functional Groups

Chemistry of Hypervalent Halogen Compounds, 2 Volume Set

Inbunden, Engelska, 2019

AvBerit Olofsson,Ilan Marek,Zvi Rappoport

14 769 kr

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The understanding of functional groups is the key to understanding organic chemistry. In the tradition of Patai's Chemistry of Functional Groups each volume treats all aspects of functional groups, touching on theoretical, analytical, synthetic, biological, and industrial aspects. Hypervalent halogen compounds, in particular iodine compounds, are very efficient and selective oxidants which tolerate a wide range of functional groups. The electrophilic properties of these reagents can also be used to introduce other functionalizations. The present volume is the first in the series to survey the properties and chemical behaviour of hypervalent iodine and bromine, their use in organic synthesis, as well as their industrial application. As with all new volumes, the chapters are first published online in Patai's Chemistry of Functional Groups. Once a volume is completed online, it is then published in print format. The printed book offers the traditional quality of the Patai Book Series, complete with an extensive index.

Produktinformation

Utgivningsdatum2019-03-15
Mått160 x 236 x 58 mm
Vikt1 905 g
FormatInbunden
SpråkEngelska
SeriePatai's Chemistry of Functional Groups
Antal sidor1 072
FörlagJohn Wiley & Sons Inc
ISBN9781119352303

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1. Fundamental aspects of structure, bonding, and the reactivity of hypervalent iodine compounds 1Halua Pinto de Magalhães, Oliver Sala, and Hans Peter Lüthi2. Structural chemistry of hypervalent iodine compounds 31Michael W. Justik3. Aspects of the chemical energetics of the hypervalent benzene-based organohalogen halosyl, halyl, and perhalyl species 119Maja Ponikvar-Svet Joel F. Liebman4. Mass spectrometry and gas-phase ion chemistry of hypervalent halogen compounds 141Richard A. J. O’hair5. NMR of hypervalent iodine compounds 187Yichen Wu and Alexandr Shafir6. Synthesis of hypervalent iodine compounds for oxidation reactions 221Viktor V. Zhdankin7. Oxidation of alcohols and amines 261Muhammet Uyanik and Kazuaki Ishihara8. Oxidative heteroatom–heteroatom bond formation 307Luis Bering and Andrey P. Antonchick9. Carbon–heteroatom bond formation mediated by hypervalent iodine 365Rafael M. Romero and Kilian Muñiz10. Halogenation and perfluoroalkylation chemistry using hypervalent halogen compounds 409Dmitry Katayev, Benson Jelier, and Antonio Togni11. Arylations promoted by hypervalent iodine reagents 461Piret Villo and Berit Olofsson12. Alkynylations and vinylations 523Durga Prasad Hari, Stefano Nicolai, and Jerome Waser13. Oxidative C−C bond formation (couplings, cyclizations, cyclopropanation, etc.) 581Toshifumi Dohi and Yasuyuki Kita14. Rearrangements and fragmentations mediated by hypervalent iodine reagents 665Sarah E. Wengryniuk, and Sylvain Canesi15. Industrial applications 707Tatsuo Kaiho and Viktor V. Zhdankin16. Hypervalent iodine compounds as precursors for biomedical radiotracers 721Sanjay Telu, Fabrice G. Siméon, Shuiyu Lu and Victor W. Pike17. Chemistry of hypervalent bromine 781Kazunori Miyamoto18. Stereoselective reactions 807Fateh V. Singh and ThomasWirth19. Photochemistry of hypervalent iodine compounds 855Kunfang Jia and Yiyun Chen20. Electrochemistry of hypervalent iodine compounds 897Robert Francke, Timo Broese, and Arend F. Roesel21. Transition metal-catalyzed reactions with iodine(III) reagents 919Gergely L. Tolnai, Zsombor Gonda, and Zoltán NovákSubject index 987