Handbook of High-resolution Spectroscopy

Professor Martin Quack, ETH Zürich, Laboratorium für Physikalische Chemie, Switzerland. Professor Frédéric Merkt, ETH Zürich, Laboratorium für Physikalische Chemie, Switzerland.

• Volume 1: Fundamentals and TheoryContributors ixPreface xvAbbreviations and Acronyms xviiMolecular Quantum Mechanics and Molecular Spectra, Molecular Symmetry, and Interaction of Matter with Radiation 1Fr´ed´eric Merkt and Martin QuackFundamentals of Rotational Spectroscopy 57Alfred BauderFundamentals of Rotation–Vibration Spectra 117Sieghard Albert, Karen Keppler Albert, Hans Hollenstein, Carine Manca Tanner and Martin QuackFundamentals of Electronic Spectroscopy 175Hans Jakob W¨orner and Fr´ed´eric MerktConventions, Symbols, Quantities, Units and Constants for High-resolution Molecular Spectroscopy 263J¨urgen Stohner and Martin QuackAnalytic Derivative Methods in Molecular Electronic Structure Theory: A New Dimension to Quantum Chemistry and its Applications to Spectroscopy 325Yukio Yamaguchi and Henry F. Schaefer IIIAb Initio Theory for Accurate Spectroscopic Constants and Molecular Properties 363David P. Tew, Wim Klopper, Rafał A. Bachorz and Christof H¨attigPrediction of Vibrational Spectra from Ab Initio Theory 389J¨urgen Breidung and Walter ThielRelativistic Electronic Structure Theory for Molecular Spectroscopy 405Remigius Mastalerz and Markus ReiherAb Initio Calculations for Rydberg States 443Martin JungenElements of Quantum Defect Theory 471Christian JungenGlobal Analytical Potential Energy Surfaces for High-resolution Molecular Spectroscopy and Reaction Dynamics 511Roberto Marquardt and Martin QuackHigh Accuracy Rotation–Vibration Calculations on Small Molecules 551Jonathan TennysonUsing Iterative Methods to Compute Vibrational Spectra 573Tucker Carrington JrIndeterminacies of Fitting Parameters in Molecular Spectroscopy 587James K. G. WatsonGroup Theory for High-resolution Spectroscopy of Nonrigid Molecules 607Melanie SchnellOrders of Magnitude and Symmetry in Molecular Spectroscopy 633Takeshi OkaFundamental Symmetries and Symmetry Violations from High-resolution Spectroscopy 659Martin QuackVolume 2: From MW To IR and UV SpectroscopyContributors ixPreface xvAbbreviations and Acronyms xviiFourier Transform Microwave Spectroscopy Measurement and Instrumentation 723Jens-Uwe GrabowNew Techniques in Microwave Spectroscopy 801Steven T. Shipman and Brooks H. PateMicrowave Spectroscopy of Large Molecules and Molecular Complexes 829Walther CaminatiTHz and Submillimeter-wave Spectroscopy of Molecular Complexes 853Keiichi Tanaka, Kensuke Harada and Koichi M.T. YamadaRotational Spectroscopy of Complexes Containing Free Radicals 897Yasuki Endo and Yoshihiro SumiyoshiFourier Transform Microwave Spectroscopy of Doped Helium Clusters 917Wolfgang J¨ager and Yunjie XuMillimeter and Submillimeter Wave Spectroscopy and Astrophysical Applications 939Lucy M. ZiurysHigh-resolution Fourier Transform Infrared Spectroscopy 965Sieghard Albert, Karen Keppler Albert and Martin QuackHigh-resolution FTIR and Diode Laser Spectroscopy of Supersonic Jets 1021Marcel Snels, Veronika Hork´a-Zelenkov´a, Hans Hollenstein and Martin QuackMass and Isotope-selective Infrared Spectroscopy 1069Michael Hippler, Eduard Miloglyadov, Martin Quack and Georg SeyfangHigh-resolution IR-laser Jet Spectroscopy of Formic Acid Dimer 1119Martina Havenith and O¨ zgu¨r BirerHigh-resolution Infrared Laser Spectroscopy and Gas Sensing Applications 1129Markus W. SigristHigh-resolution Raman Spectroscopy of Gases 1153Alfons WeberHigh-resolution Rotational Raman Coherence Spectroscopy with Femtosecond Pulses 1237Hans-Martin Frey, Dominique Kummli, Simon Lobsiger and Samuel LeutwylerHigh-resolution Microwave and Infrared Spectroscopy of Molecular Cations 1267Takayoshi AmanoElectronic Spectroscopy in the Gas Phase 1291David W. PrattElectronic Spectroscopy of Transient Molecules 1321Zohra Guennoun and John P. MaierRotationally Resolved Electronic Spectroscopy and Automatic Assignment Techniques using Evolutionary Algorithms 1345Michael Schmitt and W. Leo MeertsPrecision Laser Spectroscopy in the Extreme Ultraviolet 1373Kjeld S.E. Eikema and Wim UbachsVolume 3: Special Techniques and ApplicationsContributors ixPreface xvAbbreviations and Acronyms xviiIntroduction to Modeling High-resolution Spectra 1415Colin M. WesternSpherical Top Theory and Molecular Spectra 1437Vincent Boudon, Jean-Paul Champion, Tony Gabard, Michel Lo¨ete, Maud Rotger and Christian WengerEffective Hamiltonians for Electronic Fine Structure and Polyatomic Vibrations 1461Robert W. Field, Joshua H. Baraban, Samuel H. Lipoff and Annelise R. BeckTheory of the Jahn–Teller Effect 1517Horst K¨oppel, Lorenz S. Cederbaum and Susanta MahapatraHelium Droplets as Nanocryostats for Molecular Spectroscopy—from the Vacuum Ultraviolet to the Microwave Regime 1551Carlo Callegari and Wolfgang E. ErnstHigh-resolution Valence-shell Photoionization 1595Stephen T. PrattHigh-resolution Photoelectron Spectroscopy 1617Fr´ed´eric Merkt, Stefan Willitsch and Urs HollensteinHigh-resolution Inner-shell Photoionization, Photoelectron and Coincidence Spectroscopy 1655Catalin Miron and Paul MorinExperimental Methods in Cation Spectroscopy 1691Stefan WillitschMolecular Clusters and Noncovalent Bonds Probed by Photoionization and Photoelectron Spectroscopy 1713Klaus M¨uller-Dethlefs and Mikko RieseSpectroscopy and Reaction Dynamics of Anions 1741Roland WesterDoppler-free Laser Spectroscopy 1759Wolfgang Demtr¨oderAttosecond Spectroscopy 1781Hans Jakob W¨orner and Paul B. CorkumFemtosecond and Attosecond Light Sources and Techniques for Spectroscopy 1805Lukas Gallmann and Ursula Keller2D-Infrared Spectroscopy 1837Peter HammHigh-resolution Photofragment Translational Spectroscopy using Rydberg Tagging Methods 1859Michael N. R. Ashfold, Graeme A. King, Michael G. D. Nix and Thomas A. A. OliverPhotodissociation Dynamics of Polyatomic Molecules: Diffuse Structures and Nonadiabatic Coupling 1885Reinhard SchinkeHigh-resolution Infrared–Ultraviolet (IR–UV) Double-resonance Spectroscopy of Biological Molecules 1911E. Cristina Stanca-Kaposta and John P. SimonsMultiphoton Resonance Spectroscopy of Biological Molecules 1943Thomas H¨aber and Karl KleinermannsSpectroscopy of the Earth’s Atmosphere 1971Jean-Marie Flaud and Johannes OrphalHigh-resolution Infrared Spectroscopy of Acetylene: Theoretical Background and Research Trends 1993Michel HermanSubject Index 2027Author Index 2089