Electrophosphorescent Materials and Devices

Inbunden, Engelska, 2023

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Organic LEDs (OLEDs) in mobile displays have been in large-scale production for over a decade, and OLED-based televisions are rapidly gaining traction in the marketplace. OLEDs are on the verge of entering the solid-state lighting market in a big way. The OLED technology gives higher color purity and is more efficient than any of the competing technologies. When produced at scale, OLEDs are also economical. A key limitation in the development of OLEDs was the efficient conversion of all of the electrical energy put into the device into light. Until the late 1990s, the maximum efficiency of OLEDs was limited to 25% (photons/electrons), but this limitation was removed and OLEDs with 100% efficiency were reported in the early 2000s. This advance in OLED technology was driven by the author of this book. He and his collaborators developed electrophosphorescence, which is essential in reaching the 100% efficiency that is now commonplace in commercial devices.

Produktinformation

Utgivningsdatum2023-12-14
Mått152 x 229 x undefined mm
Vikt453 g
FormatInbunden
SpråkEngelska
Antal sidor1 082
FörlagJenny Stanford Publishing
ISBN9789814877343

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Mark E. Thompson received his BS in chemistry in 1980 from the University of California, Berkeley, and his PhD in chemistry in 1985 from the California Institute of Technology. He was a postdoctoral fellow at Oxford University and is currently the Ray R. Irani Chair of Chemistry at the University of Southern California. His research involves the study of materials and devices for electroluminescence, photovoltaics and solar cells, chemical/biological sensing, and catalysis. Prof. Thompson is the author of approximately 400 papers in refereed professional journals and holds more than 250 patents primarily in the areas of optoelectronic applications, such as light-emitting devices and solar cells.

1. Highly Efficient Phosphorescent Emission from Organic Electroluminescent DevicesMarc A. Baldo, D. F. O’Brien, Y. You, A. Shoustikov, Scott Sibley, Mark E. Thompson, and Stephen R. Forrest2. Improved Energy Transfer in Electrophosphorescent DevicesD. F. O’Brien, Marc A. Baldo, Mark E. Thompson, and Stephen R. Forrest3. Efficient, Saturated Red Organic Light Emitting Devices Based on Phosphorescent Platinum(II) PorphyrinsRaymond C. Kwong, Scott Sibley, Timur Dubovoy, Marc Baldo, Stephen R. Forrest, and Mark E. Thompson4. Excitonic Singlet-Triplet Ratio in a Semiconducting Organic Thin FilmMarc A. Baldo, D. F. O’Brien, Mark E. Thompson, and Stephen R. Forrest5. Very High-Efficiency Green Organic Light-Emitting Devices Based on ElectrophosphorescenceMarc A. Baldo, Sergey Lamansky, Paul E. Burrows, Mark E. Thompson, and Stephen R. Forrest6. Organic Light-Emitting Devices Based on Phosphorescent Hosts and DyesRaymond C. Kwong, Sergey Lamansky, and Mark E. Thompson7. High-Efficiency Organic Electrophosphorescent Devices with tris(2-Phenylpyridine)Iridium Doped into Electron-Transporting MaterialsChihaya Adachi, Marc A. Baldo, Stephen R. Forrest, and Mark E. Thompson8. High-Efficiency Fluorescent Organic Light-Emitting Devices Using a Phosphorescent SensitizerMarc A. Baldo, Mark E. Thompson, and Stephen R. Forrest9. Nearly 100% Internal Phosphorescence Efficiency in an Organic Light Emitting DeviceChihaya Adachi, Marc A. Baldo, Mark E. Thompson, and Stephen R. Forrest10. Endothermic Energy Transfer: A Mechanism for GeneratingVery Efficient High-Energy Phosphorescent Emission in Organic MaterialsChihaya Adachi, Raymond C. Kwong, Peter Djurovich, Vadim Adamovich, Marc A. Baldo, Mark E. Thompson, and Stephen R. Forrest11. High-Efficiency Yellow Double-Doped Organic Light-Emitting Devices Based on Phosphor-Sensitized FluorescenceBrian W. D’Andrade, Marc A. Baldo, Chihaya Adachi, Jason Brooks, Mark E. Thompson, and Stephen R. Forrest12. High-Efficiency Red Electrophosphorescence DevicesChihaya Adachi, Marc A. Baldo, Stephen R. Forrest, Sergey Lamansky, Mark E. Thompson, and Raymond C. Kwong13. Highly Phosphorescent Bis-Cyclometalated Iridium Complexes: Synthesis, Photophysical Characterization, and Use in Organic Light Emitting DiodesSergey Lamansky, Peter Djurovich, Drew Murphy, Feras Abdel-Razzaq, Hae-Eun Lee, Chihaya Adachi, Paul E. Burrows, Stephen R. Forrest, and Mark E. Thompson14. Synthesis and Characterization of Phosphorescent Cyclometalated Iridium ComplexesSergey Lamansky, Peter Djurovich, Drew Murphy, Feras Abdel-Razzaq, Raymond Kwong, Irina Tsyba, Manfred Bortz, Becky Mui, Robert Bau, and Mark E. Thompson15. Synthesis and Characterization of Phosphorescent Cyclometalated Platinum ComplexesJason Brooks, Yelizaveta Babayan, Sergey Lamansky, Peter I. Djurovich, Irina Tsyba, Robert Bau, and Mark E. Thompson16. White Light Emission Using Triplet Excimers in Electrophosphorescent Organic Light-Emitting DevicesBrian W. D’Andrade, Jason Brooks, Vadim Adamovich, Mark E. Thompson, and Stephen R. Forrest17. Electrophosphorescent p–i–n Organic Light-Emitting Devices for Very-High-Efficiency Flat-Panel DisplaysMartin Pfeiﬀer, Stephen R. Forrest, Karl Leo, and Mark E. Thompson18. Cyclometalated Ir Complexes in Polymer Organic Light-Emitting DevicesSergey Lamansky, Peter I. Djurovich, Feras Abdel-Razzaq, Simona Garon, Drew L. Murphy, and Mark E. Thompson19. High Efficiency Single Dopant White Electrophosphorescent Light Emitting DiodesVadim Adamovich, Jason Brooks, Arnold Tamayo, Alex M. Alexander, Peter I. Djurovich, Brian W. D’Andrade, Chihaya Adachi, Stephen R. Forrest, and Mark E. Thompson20. High Operational Stability of Electrophosphorescent DevicesRaymond C. Kwong, Matthew R. Nugent, Lech Michalski, Tan Ngo, Kamala Rajan, Yeh-Jiun Tung, Michael S. Weaver, Theodore X. Zhou, Michael Hack, Mark E. Thompson, Stephen R. Forrest, and Julie J. Brown21. Controlling Exciton Diffusion in Multilayer White Phosphorescent Organic Light Emitting DevicesBrian W. D’Andrade, Mark E. Thompson, and Stephen R. Forrest22. Blue Organic Electrophosphorescence Using Exothermic Host–Guest Energy TransferRussell J. Holmes, Stephen R. Forrest, Yeh-Jiun Tung, Raymond C. Kwong, Julie J. Brown, Simona Garon, and Mark E. Thompson23. Efficient, Deep-Blue Organic Electrophosphorescence by Guest Charge TrappingRussell J. Holmes, Brian W. D’Andrade, Stephen R. Forrest, Xiaofan Ren, Jian Li, and Mark E. Thompson24. Synthesis and Characterization of Facial and Meridional Tris-cyclometalated Iridium(III) ComplexesArnold B. Tamayo, Bert D. Alleyne, Peter I. Djurovich, Sergey Lamansky, Irina Tsyba, Nam N. Ho, Robert Bau, and Mark E. Thompson25. Phosphorescence Quenching by Conjugated PolymersMadhusoodhanan Sudhakar, Peter I. Djurovich, Thieo E. Hogen-Esch, and Mark E. Thompson26. Simultaneous Light Emission from a Mixture of Dendrimer Encapsulated Chromophores: A Model for Single-Layer Multichromophoric Organic Light-Emitting DiodesPaul Furuta, Jason Brooks, Mark E. Thompson, and Jean M. J. Fréchet27. Ultrahigh Energy Gap Hosts in Deep Blue Organic Electrophosphorescent DevicesXiaofan Ren, Jian Li, Russell J. Holmes, Peter I. Djurovich, Stephen R. Forrest, and Mark E. Thompson28. Saturated Deep Blue Organic Electrophosphorescence Using a Fluorine-Free EmitterRussell J. Holmes, Stephen R. Forrest, Tissa Sajoto, Arnold Tamayo, Peter I. Djurovich, Mark E. Thompson, Jason Brooks, Yeh-Jiun Tung, Brian W. D’Andrade, Michael S. Weaver, Raymond C. Kwong, and Julie J. Brown29. Excimer and Electron Transfer Quenching Studies of a Cyclometalated Platinum ComplexBiwu Ma, Peter I. Djurovich, and Mark E. Thompson30. Synthetic Control of Excited-State Properties in Cyclometalated Ir(III) Complexes Using Ancillary LigandsJian Li, Peter I. Djurovich, Bert D. Alleyne, Muhammed Yousufuddin, Nam N. Ho, J. Christopher Thomas, Jonas C. Peters, Robert Bau, and Mark E. Thompson31. Cationic Bis-cyclometalated Iridium(III) Diimine Complexes and Their Use in Efficient Blue, Green, and Red Electroluminescent DevicesArnold B. Tamayo, Simona Garon, Tissa Sajoto, Peter I. Djurovich, Irina M. Tsyba, Robert Bau, and Mark E. Thompson32. Blue and Near-UV Phosphorescence from Iridium Complexes with Cyclometalated Pyrazolyl or N-Heterocyclic Carbene LigandsTissa Sajoto, Peter I. Djurovich, Arnold Tamayo, Muhammed Yousufuddin, Robert Bau, Mark E. Thompson, Russell J. Holmes, and Stephen R. Forrest33. Synthetic Control of Pt··· Pt Separation and Photophysics of Binuclear Platinum ComplexesBiwu Ma, Jian Li, Peter I. Djurovich, Muhammed Yousufuddin, Robert Bau, and Mark E. Thompson34. Platinum Binuclear Complexes as Phosphorescent Dopants for Monochromatic and White Organic Light-EmittingDiodesBiwu Ma, Peter I. Djurovich, Simona Garon, Bert Alleyne, and Mark E. Thompson35. Management of Singlet and Triplet Excitons for Efficient White Organic Light-Emitting DevicesYiru Sun, Noel C. Giebink, Hiroshi Kanno, Biwu Ma, Mark E. Thompson, and Stephen R. Forrest36. Highly Efficient, Near-Infrared Electrophosphorescence from a Pt–Metalloporphyrin ComplexCarsten Borek, Kenneth Hanson, Peter I. Djurovich, Mark E. Thompson, Kristen Aznavour, Robert Bau, Yiru Sun, Stephen R. Forrest, Jason Brooks, Lech Michalski, and Julie Brown37. Intrinsic Luminance Loss in Phosphorescent Small-Molecule Organic Light Emitting Devices due to Bimolecular Annihilation ReactionsNoel C. Giebink, Brian W. D’Andrade, Michael S. Weaver, P. B. Mackenzie, Julie J. Brown, Mark E. Thompson, and Stephen R. Forrest38. Blue Light Emitting Ir(III) Compounds for OLEDs: New Insights into Ancillary Ligand Eﬀects on the Emitting Triplet StateAndreas F. Rausch, Mark E. Thompson, and Hartmut Yersin39. Temperature Dependence of Blue Phosphorescent Cyclometalated Ir(III) ComplexesTissa Sajoto, Peter I. Djurovich, Arnold B. Tamayo, Jonas Oxgaard, William A. Goddard III, andMark E. Thompson40. Study of Energy Transfer and Triplet Exciton Diﬀusion in Hole-Transporting Host MaterialsChao Wu, Peter I. Djurovich, and Mark E. Thompson41. Synthesis and Characterization of Phosphorescent Three-Coordinate Cu(I)–NHC ComplexesValentina A. Krylova, Peter I. Djurovich, Matthew T. Whited, and Mark E. Thompson42. A Codeposition Route to CuI–Pyridine Coordination Complexes for Organic Light-Emitting DiodesZhiwei Liu, Munzarin F. Qayyum, Chao Wu, Matthew T. Whited, Peter I. Djurovich, Keith O. Hodgson, Britt Hedman, Edward I. Solomon, and Mark E. Thompson43. Structural and Photophysical Studies of Phosphorescent Three-Coordinate Copper(I) Complexes Supported by an N-Heterocyclic Carbene LigandValentina A. Krylova, Peter I. Djurovich, Jacob W. Aronson, Ralf Haiges, Matthew T. Whited, and Mark E. Thompson44. Phosphorescence versus Thermally Activated Delayed Fluorescence: Controlling Singlet–Triplet Splitting in Brightly Emitting and Sublimable Cu(I) CompoundsMarkus J. Leitl, Valentina A. Krylova, Peter I. Djurovich, Mark E. Thompson, and Hartmut Yersin45. Control of Emission Colour with N-Heterocyclic Carbene (NHC) Ligands in Phosphorescent Three-Coordinate Cu(I) ComplexesValentina A. Krylova, Peter I. Djurovich, Brian L. Conley, Ralf Haiges, Matthew T. Whited, Travis J. Williams, and Mark E. Thompson46. Synthesis and Characterization of Phosphorescent Platinum and Iridium Complexes with Cyclometalated CorannuleneJohn W. Facendola, Martin Seifrid, Jay Siegel, Peter I. Djurovich, and Mark E. Thompson47. Understanding and Predicting the Orientation of Heteroleptic Phosphors in Organic Light-Emitting MaterialsMatthew J. Jurow, Christian Mayr, Tobias D. Schmidt, Thomas Lampe, Peter I. Djurovich, Wolfgang Brütting, and Mark E. Thompson48. Deep Blue Phosphorescent Organic Light-Emitting Diodes with Very High Brightness and EfficiencyJaesang Lee, Hsiao-Fan Chen, Thilini Batagoda, Caleb Coburn, Peter I. Djurovich, Mark E. Thompson, and Stephen R. Forrest49. Hot Excited State Management for Long-Lived Blue Phosphorescent Organic Light-Emitting DiodesJaesang Lee, Changyeong Jeong, Thilini Batagoda, Caleb Coburn, Mark E. Thompson, and Stephen R. Forrest50. Eliminating Nonradiative Decay in Cu(I) Emitters: > 99% Quantum Efficiency and Microsecond LifetimeRasha Hamze, Jesse L. Peltier, Daniel Sylvinson, Moonchul Jung, Jose Cardenas, Ralf Haiges, Michele Soleilhavoup, Rodolphe Jazzar, Peter I. Djurovich, Guy Bertrand, and Mark E. Thompson51. Rapid Multiscale Computational Screening for OLED Host MaterialsDaniel Sylvinson M. R., Hsiao-Fan Chen, Lauren M. Martin, Patrick J. G. Saris, and Mark E. Thompson52. “Quick-Silver” from a Systematic Study of Highly Luminescent, Two-Coordinate, d10 Coinage Metal ComplexesRasha Hamze, Shuyang Shi, Savannah C. Kapper, Daniel Sylvinson Muthiah Ravinson, Laura Estergreen, Moon-Chul Jung, Abegail C. Tadle, Ralf Haiges, Peter I. Djurovich, Jesse L. Peltier, Rodolphe Jazzar, Guy Bertrand, Stephen E. Bradforth, and Mark E. Thompson53. Highly Efficient Photo- and Electroluminescence from Two-Coordinate Cu(I) Complexes Featuring Nonconventional N-Heterocyclic CarbenesShuyang Shi, Moon Chul Jung, Caleb Coburn, Abegail Tadle, Daniel Sylvinson M. R., Peter I. Djurovich, Stephen R. Forrest, and Mark E. Thompson54. Platinum-Functionalized Random Copolymers for Use in Solution-Processible, Efficient, Near-White Organic Light-Emitting DiodesPaul T. Furuta, Lan Deng, Simona Garon, Mark E. Thompson, and Jean M. J. Fréchet