Spectra of Atoms and Molecules

Inbunden, Engelska, 2016

Av Peter F. Bernath, Virginia) Bernath, Peter F. (Professor of Chemistry and Biochemistry, Professor of Chemistry and Biochemistry, Old Dominion University in Norfolk

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This third edition of Peter Bernath's successful Spectra of Atoms and Molecules is designed to provide advanced undergraduates and graduate students a working knowledge of the vast field of spectroscopy. Also of interest to chemists, physicists, astronomers, atmospheric scientists, and engineers, this volume emphasizes the fundamental principles of spectroscopy with the primary goal of teaching the interpretation of spectra. Features include a presentation of group theory needed to understand spectroscopy, detailed worked examples and a large number of excellent problems at the end of each chapter. Prof. Bernath provides a large number of diagrams and spectra which have been specifically recorded for this book. Molecular symmetry, matrix representation of groups, quantum mechanics, and group theory are among the topics covered; atomic, rotational, vibrational, electronic and Raman spectra are analyzed. Bernath's clear treatment of the confusing topic of line strengths as needed for quantitative applications is featured.This much-needed new edition has been updated to include the 2010 CODATA revision of physical constants, and a large number of corrections and clarifications. Responding to student requests, the main new feature is the addition of detailed worked examples in each chapter. Spectra of Atoms and Molecules, 3e will help demystify spectroscopy by showing readers the necessary steps in a derivation, as well as the final result.

Produktinformation

Utgivningsdatum2016-01-14
Mått257 x 180 x 27 mm
Vikt1 021 g
FormatInbunden
SpråkEngelska
Antal sidor484
Upplaga3
FörlagOUP USA
ISBN9780199382576

Tillhör följande kategorier

Fysik inom Naturvetenskap och teknik
Analytisk kemi inom Naturvetenskap och teknik
Fysikalisk kemi inom Naturvetenskap och teknik

Introduction1.1 Waves, Particles, and Units1.2 The Electromagnetic Spectrum1.3 Interaction of Radiation with MatterMolecular Symmetry 2.1 Symmetry Operations2.2 Groups2.3 Notation for Point Groups3 Matrix Representation of Groups 3.1 Vectors and Matrices3.2 Symmetry Operations and Position Vector Basis3.3 Symmetry Operators and Atomic Basis Vectors 3.4 Symmetry Operators and Basis Functions3.5 Equivalent, Reducible, and Irreducible Representations3.6 Great Orthogonality Theorem 3.7 Character Tables Quantum Mechanics and Group Theory 4.1 Matrix Representation of the Schr¨odinger Equation4.2 Born-Oppenheimer Approximation4.3 Symmetry of the Hamiltonian Operator4.4 Projection Operators 4.5 Direct Product Representations4.6 Integrals and Selection RulesAtomic Spectroscopy 5.1 Background5.2 Angular Momentum5.3 The Hydrogen Atom and One-Electron Spectra5.4 Many-Electron Atoms 5.5 Selection Rules 5.6 Atomic Spectra 5.7 Intensity of Atomic Lines5.8 Zeeman Effect 5.9 Stark Effect Rotational Spectroscopy6.1 Rotation of Rigid Bodies6.2 Diatomic and Linear Molecules6.3 Rotational Line Intensities for Diatomic and Linear Molecules6.4 Symmetric Tops 6.5 Asymmetric Tops6.6 Structure Determination Vibrational Spectroscopy 7.1 Diatomic Molecules7.2 Vibrational Motion of Polyatomic Molecules 7.3 Selection Rules for Vibrational Transitions 7.4 Vibrational Spectra of Polyatomic Linear Molecules 7.5 Vibrational Spectra of Symmetric Tops 7.6 Vibrational Spectra of Spherical Tops 7.7 Vibrational Spectra of Asymmetric Tops7.8 Vibration-Rotation Line Intensities 7.9 Fermi and Coriolis Perturbations7.10 Inversion Doubling and Fluxional BehaviorLight Scattering and the Raman Effect 8.1 Background 8.2 Rotational Raman Effect 8.3 Vibration-Rotation Raman Spectroscopy 8.4 Rayleigh and Raman Intensities Electronic Spectroscopy of Diatomics9.1 Orbitals and States 9.2 Vibrational Structure9.3 Rotational Structure of Diatomic Molecules9.4 The Symmetry of Diatomic Energy Levels: Parity9.5 Rotational Line Intensities 9.6 Dissociation, Photodissociation, and Predissociation Electronic Spectroscopy of Polyatomics 10.1 Orbitals and States10.2 Vibrational Structure of Electronic Transitions10.3 Vibronic Coupling: The Herzberg-Teller Effect10.4 Jahn-Teller Effect and Conical Intersections10.5 Renner-Teller Effect10.6 Nonradiative Transitions: Jablonski Diagram 10.7 Photoelectron Spectroscopy 10.8 Rotational Structure: H2CO and HCN 10.9 Intensity of Transitions