Inorganic Chemistry

From Periodic Classification to Crystals

Inbunden, Engelska, 2017

Av Robert Valls, France) Valls, Robert (University of Aix-Marseille

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Using classification, diagrams and crystallography elements, we describe in this book the bonds in the crystals using the basic patterns. The use of various criteria such as ionicity character of the bonds, the use of hard sphere models, the Pauling rules and the spatial availability of ions all together make it possible to better understand the spatial organization of typical crystals. Through original representations, the structure and the nature of the bonds in binary crystals of MX- and MX2- types as well as the ternary crystals of the perovskite and spinel type are studied.

Produktinformation

Utgivningsdatum2017-11-14
Mått163 x 239 x 20 mm
Vikt544 g
FormatInbunden
SpråkEngelska
Antal sidor288
FörlagISTE Ltd and John Wiley & Sons Inc
ISBN9781786302540

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Acknowledgments ixIntroduction xiChapter 1. Knowledge of the Periodic Table 11.1. Presentation of the periodic table 11.2. Construction of the periodic table 21.2.1. History 21.2.2. Structuring of the periodic table 101.2.3. Analysis of various classifications 141.2.4. Abundance of elements 191.3. Reading the classification 241.3.1. Atomic radius 251.3.2. Electronegativity 281.3.3. Ionization potential 311.3.4. Electron binding energy 341.4. Understanding ions through the classification 371.4.1. The nature and valence of ions through the classification 371.4.2. Radius of ions through the classification 411.4.3. Polarizability 441.4.4. The radii of ions in solids 46Chapter 2. Knowledge of Metallic Crystals 532.1. Properties of metals 532.1.1. Characteristics of the metallic bond 542.1.2. Conductivity and the melting temperature of elements 562.2. Study of packing in metals 592.2.1. Formation of planar packing 602.2.2. Crystal formation 622.2.3. Counting atoms in a unit cell 682.2.4. Packing density 712.2.5. Designation of planes in a crystal 732.2.6. Surface density 762.3. Representation of metallic crystals 812.3.1. Definition of the unit cell 812.3.2. Geometry of simple polyhedrons 962.3.3. The sites 1002.4. Packings and diagrams 1032.4.1. Reading the diagrams 1052.4.2. Solid solutions 1092.4.3. Intermetallic compounds 1122.4.4. Simple phase diagrams 113Chapter 3. Knowledge of Ionic Crystals 1253.1. Description of ionic to covalent crystals 1253.2. Pauling’s rules 1293.2.1. The ionic character of a bond according to Pauling 1303.2.2. Pauling’s first rule: coordinated polyhedra 1333.2.3. Pauling’s second rule: electrostatic valence principle 1413.2.4. Pauling’s third rule: connections of polyhedra 1443.2.5. Pauling’s fourth rule: separation of cations 1463.2.6. Pauling’s fifth rule: homogeneity of the environment 1473.2.7. Presentation of criteria employed 1473.3. Geometry of binary crystals of MXn type 1493.3.1. Presentation of the mentioned compounds 1493.3.2. Study of cesium chloride 1513.3.3. Study of sodium chloride 1593.3.4. Study of zinc sulfide (sphalerite) 1713.3.5. Study of zinc sulfide (wurtzite) 1783.3.6. Study of nickel arsenide 1853.4. Geometry of binary crystals of MX2 type 1913.4.1. Study of calcium fluoride 1913.4.2. Study of lithium oxide 1963.4.3. Study of rutile 1993.4.4. Study of cadmium iodide 2063.4.5. Study of cadmium chloride 2123.5. Review of characteristics of binary structures 2153.5.1. Crystalline characteristics 2153.5.2. Characteristics of availability 2163.5.3. Characteristics of the unit cells 2173.5.4. Characteristics of the families of compounds 2193.6. Geometry of ternary crystals of ABnOm type 2213.6.1. Study of SrTiO3 perovskite 2213.6.2. Study of MgAl2O4 spinel 227Appendix 237Bibliography 239Index 255