Hypervalent Iodine Compounds

Nyhet

Synthesis and Applications

Inbunden, Engelska, 2026

Av Viktor V. Zhdankin, USA) Zhdankin, Viktor V. (University of Minnesota Duluth, MN

3 259 kr

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Produktinformation

Utgivningsdatum2026-05-21
FormatInbunden
SpråkEngelska
Antal sidor928
FörlagJohn Wiley & Sons Inc
ISBN9781394307616

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Preface 1. Introduction and General Overview of Polyvalent Iodine Compounds 1.1. Introduction1.2. Classification and Nomenclature of Polyvalent Iodine Compounds1.3. Hypervalent Bonding1.4. General Structural Features1.5. General Principles of Reactivity2. Preparation, Structure, and Properties of Polyvalent Iodine Compounds2.1. Introduction2.2. Iodine(III) Compounds2.3. Iodine(V) Compounds2.4. Iodine(VII) Compounds3. Applications of Iodine(III) Reagents in Halogenations and Oxidative Functionalizations of Organic Substrates3.1. Introduction3.2. Fluorinations3.3. Chlorinations3.4. Brominations3.5. Iodinations3.6. Oxidation of Alcohols3.7. Oxidative Functionalization of Carbonyl Compounds3.8. Oxidative Functionalization of Silyl Enol Ethers3.9. Oxidative Functionalization of Alkenes and Alkynes3.10. Oxidations at the Benzylic or Allylic Position3.11. Oxidative Functionalization of Aromatic Compounds3.12. Oxidative Dearomatization of Phenols and Related Substrates3.13. Oxidative Coupling of Aromatic Substrates3.14. Oxidative Heterocyclizations3.15. Oxidative Rearrangements3.16. Radical Fragmentations and Cyclizations Initiated by [Bis(acyloxy)iodo]arenes3.17. Oxidations at Nitrogen, Sulfur, and other Heteroatoms3.18. Reactions via Alkyliodine(III) Intermediates: Oxidative Deiodination of Alkyliodides 3.19. Transition Metal Catalyzed Oxidations4. Applications of Iodine(III) Reagents in Reactions Resulting in Formation of New C-N, C-S, C-Se, and C-Te Bonds4.1. Introduction4.2. Azidations4.3. Amidations and Aminations4.4. Thiocyanations and Arylselenations4.5. Reactions of Iodonium salts and C-Substituted Benziodoxoles Resulting in Formation of New C-N, C-S, and C-Se bonds5. Applications of Iodonium Salts, C-Substituted Benziodoxoles, and Iodonium Ylides in Organic Synthesis5.1. Introduction5.2. Reactions of Iodonium Salts5.3. Reactions of C-Substituted Benziodoxoles5.4. Reactions of Iodonium Ylides6. Applications of Hypervalent Iodine(V) Reagents in Organic Synthesis6.1. Introduction6.2. Synthetic Applications of Non-Cyclic and Pseudocyclic Iodylarenes Ylides6.3. Synthetic Applications of 2-Iodoxybenzoic Acid (IBX)6.4. IBX Derivatives and Analogs6.5. Dess-Martin Periodinane (DMP)7. Applications of Inorganic Polyvalent Iodine Compounds in Organic Synthesis7.1. Introduction7.2. Derivatives of Iodine in Oxidation State +17.3. Synthetic Applications of Inorganic Iodine(III) Reagents7.4. Synthetic Applications of Inorganic Iodine(V) Reagents7.5. Synthetic Applications of Iodine(VII) Reagents8. Hypervalent Iodine Catalysis8.1. Introduction8.2. Catalytic Cycles Based on Iodine(III) Species8.3. Catalytic Cycles Based on Iodine(V) Species8.4. Tandem Catalytic Systems Involving Hypervalent Iodine and other co-Catalysts8.5. Catalytic Cycles Involving Iodide Anion or Elemental Iodine as Precatalysts8.6. Electrochemical Reactions Involving Hypervalent Iodine Mediators9. Recyclable Hypervalent Iodine Reagents9.1. Introduction9.2. Polymer-Supported Iodine(III) Reagents9.3. Polymer-Supported Iodine(V) Reagents9.4. Recyclable Nonpolymeric Hypervalent Iodine(III) Reagents9.5. Recyclable Nonpolymeric Hypervalent Iodine(V) Reagents9.6. Recyclable Iodoarene-Based Catalysts and Bifunctional Catalytic Systems10. Reactions of Hypervalent Iodine Reagents in Green Solvents and under Solvent-Free Conditions10.1. Introduction10.2. Reactions of Hypervalent Iodine Reagents in Water10.3. Reactions of Hypervalent Iodine Reagents in Recyclable Organic Solvents10.4. Reactions of Hypervalent Iodine Reagents Under Solvent-Free Conditions11. Industrial and Biomedical Applications of Polyvalent Iodine Compounds11.1. Introduction11.2. Applications of Inorganic Polyvalent Iodine Derivatives11.3. Applications of Hypervalent Iodine(III) Compounds as Polymerization Initiators11.4 Applications of Hypervalent Iodine Compounds as Industrial Reagents11.5. Application of Iodonium Salts for Fluoridation in Positron Emission Tomography (PET)11.6. Biological Activity of Polyvalent Iodine Compounds12. Index

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