Functional Metal-Organic Frameworks

Audience This book is interesting to a diverse group of scientists, including chemists, materials scientists, chemical engineers and any scientist who is working on supramolecular chemistry of MOFs and designing functional materials. Ali Morsali is Master in Inorganic Chemistry in Tarbiat Modares University, Tehran, Iran. He obtained his PhD in 2003 in Inorganic Chemistry from the same university. He has published more than 400 articles in international journals as well as 5 patents. He has received numerous national awards. Amongst his research interests are coordination chemistry and metal-organic frameworks. He is the co-author of Main Group Metal Coordination Polymers and Pillared Metal-Organic Frameworks (Wiley-Scrivener 2017, 2019 respectively). Sayed Ali Akbar Razavi received his BSc in pure chemistry in 2014 from Sharif University of Technology and his MSc in inorganic chemistry in 2017 from Tarbiat Modares University, Tehran, Iran. Currently, he is a PhD student under supervision of Prof. Ali Morsali. His research interest focuses on functional metal–organic frameworks.

• Preface ix1 Introduction to Functional Metal–Organic Frameworks 11.1 Coordination Polymers 11.2 Metal–Organic Frameworks 41.3 Functional Metal–Organic Frameworks 6References 112 Amine Decorated Metal–Organic Frameworks 152.1 General Chemical Properties of Amine Function 152.2 Function–Application Properties 162.3 Function–Structure Properties 30References 313 Azo and Azine Decorated Metal–Organic Frameworks 373.1 General Chemical Properties of Azine and Azo Functions 373.2 Function–Application Properties 373.3 Function-Structure Properties 47References 504 Imidazolium and Pyridinium Decorated Metal-Organic Frameworks 554.1 Imidazolium Functionalized Metal–Organic Frameworks 554.1.1 General Chemical Properties of Imidazolium Function 554.1.2 Function–Application Properties 564.1.3 Function–Structure Properties 634.2 Pyridinium Functionalized Metal–Organic Frameworks 644.2.1 General Chemical Properties of Pyridinium Function 644.2.2 Function–Application Properties 654.2.3 Function–Structure Properties 71References 725 Heterocyclic Azine Decorated Metal-Organic Frameworks 795.1 General Chemical Properties of Heterocyclic Azine Functions 795.2 Function–Application Properties 815.3 Function–Structure Properties 95References 1006 Heterocyclic Azole Decorated Metal-Organic Frameworks 1076.1 General Chemical Properties of Heterocyclic Azole Functions 1076.2 Function–Application Properties 1086.3 Function–Structure Properties 118References 1257 Functional Metal–Organic Frameworks by Oxygen and Sulfur Based Functions 1337.1 Functionalized Metal–Organic Frameworks by Oxygen Based Functions 1337.1.1 Function–Application Properties 1337.1.2 Function–Structure Properties 1407.2 Functionalized Metal–Organic Frameworks by Sulfur Based Functions 1427.2.1 Functionalized Metal–Organic Frameworks by Thiol and Sulfide Functions 1427.2.2 Functionalized Metal–Organic Frameworks by Sulfonate-Sulfonic Acid Function 1497.2.3 Functionalized Metal–Organic Frameworks by Other S-Based Functions 155References 1568 Urea and Amide Decorated Metal-Organic Frameworks 1658.1 Functionalized Metal–Organic Frameworks by Amide Function 1668.1.1 General Chemical Properties of Amide Function 1668.1.2 Function–Application Properties 1668.1.3 Function–Structure Properties 1788.2 Functionalized Metal–Organic Frameworks by Urea Function 1808.2.1 General Chemical Properties of Urea Function 1808.2.2 Function–Application Properties 1828.2.3 Structure–Function Properties 1868.3 Functionalized Metal–Organic Frameworks by Squaramide Function 189References 1929 Carbonyl, Carboxy and Imide Functionalized Metal–Organic Frameworks 2019.1 Functionalized Metal–Organic Frameworks by Carbonyl Function 2019.1.1 General Chemical Properties of Carbonyl Functional Group 2019.1.2 Function–Application Properties 2029.1.3 Function–Structure Properties 2069.2 Functionalized Metal–Organic Frameworks by Carboxy Function 2079.2.1 General Chemical Properties of Carboxy Function 2079.2.2 Synthesis of Functionalized Metal-Organic Frameworks with Free Carboxy Function 2089.2.3 Function–Application Properties 2099.2.4 Function–Structure Properties 2139.3 Functionalized Metal–Organic Frameworks by Imide Function 2169.3.1 General Chemical Properties of Imide Function 2169.3.2 Function–Application Properties 218References 22410 Fluorine and Phosphonate Functional Metal–Organic Frameworks 23110.1 Functionalized Metal–Organic Frameworks by Phosphonic Acid/Phosphonate Functions 23110.2 Functionalized Metal–Organic Frameworks by Fluorine Function 233References 234Index 239