Enantioselective Organocatalysis III

Nyhet

Catalysts, Reactions and Applications

Inbunden, Engelska, 2025

Av Peter I. Dalko, France) Dalko, Peter I. (ESPCI, Chimie Organique, Paris

6 349 kr

Beställningsvara. Skickas inom 11-20 vardagar

Fri frakt för medlemmar vid köp för minst 249 kr.

Updated reference on the field of organocatalysis explaining the many advances made in the past 10 years Enantioselective Organocatalysis III presents easily accessible, summarized information on organocatalysis, from computational aspects to non-conventional strategies, with complete coverage of the main advances in the field in the past 10 years. The book is the continuation of Comprehensive Enantioselective Organocatalysis, retaining the main features of its predecessor but with a larger number of concise chapters. Experimental procedures are not presented in this edition as most of them are similar to those already discussed in the previous edition. Edited by a highly qualified researcher and contributed to by experts in the field, Enantioselective Organocatalysis III includes information on: Aminocatalysis-3 selected examples of aminocatalytic direct alpha-heteroatom functionalization and direct alpha-alkylationOrganocatalytic dynamic kinetic resolution and organocatalysis in carbohydrate synthesis and polymer scienceLight-controlled organocatalysis by bifunctional single-catalyst systems and dual photo/organocatalytic strategies in asymmetric synthesisStrategies towards asymmetric organocatalysis at parts-per-million loadings and emerging organocatalyst classes from renewable sourcesActivation modes in asymmetric anion-binding catalysis and transformations with chiral phase-transfer catalystsAppealing to a broad readership, Enantioselective Organocatalysis III is an essential reference for chemists and other researchers seeking to stay on top this rapidly developing field.

Produktinformation

Utgivningsdatum2025-12-31
Mått170 x 244 x undefined mm
FormatInbunden
SpråkEngelska
Antal sidor1 824
FörlagWiley-VCH Verlag GmbH
ISBN9783527353408

Tillhör följande kategorier

Peter I. Dalko completed his graduate studies at the Technical University of Budapest (BME) and earned his PhD at Paris XI, France. He currently works at the Paris Cité University, France, (CNRS). His group focuses on the development of enantiocatalytic reactions for organic synthesis, the design and application of light-sensitive molecular probes allowing accurate four-dimensional control of biological events in complex tissues, and on the preparation of remotely controllable drug delivery systems with imaging ability.

1. AMINOCATALYSIS1.1 Explaining Anomalies in Enamine Catalysis: "Downstream Species" as a New Paradigm for Stereocontrol 1.2 Synergistic Strategies in Aminocatalysis1.3 New trends in amino Acid-derived and Peptides Organocatalysts 1.4 Recent advances in amine catalyzed organocatalytic transformations2. ENANTIOSELECTIVE CARBONYL CATALYSIS ENABLED BY CHIRAL ALDEHYDES3. HYDROGEN-BOND DONOR CATALYSIS3.1 Non-Classical C-H center dot center dot center dot X Hydrogen Bonding and Its Role in Asymmetric Organocatalysis3.2 Chiral guanidines and thiourea derivatives in asymmetric synthesis 3.3 Squaramide-Catalyzed Asymmetric Reactions 3.4 Recent advances in asymmetric reactions catalyzed by chiral phosphoric acids3.5 Dual Bronsted-acid Organocatalysis: Cooperative Asymmetric Catalysis with Combined Phosphoric and Carboxylic Acids 3.6 Brønsted acid catalysts and ?silylium? Lewis acid precatalysts Imidodiphosphorimidates (IDPis) 3.7 Stronger Bronsted Acids: Recent Progress (Akiyama, T and Mori, K)4. PHOSPHINE ORGANOCATALYSIS5. ION-PAIRING CATALYSIS5.1 Activation Modes in Asymmetric Anion-Binding Catalysis5.2 Asymmetric counteranion-directed catalysis (ACDC) 5.3 Phosphonium Salts in Asymmetric Catalysis: A Journey in a Decade's Extensive Research Work 5.4 Recent Progress in Asymmetric Ion-Pairing Catalysis with Ammonium Salts6. PHASE-TRANSFER CATALYSTS6.1 Design of high-performance chiral phase-transfer catalysts with privileged structures 6.2 Assisted by Hydrogen-Bond Donors: Cinchona Quaternary Salts as Privileged Chiral Catalysts for Phase-Transfer Reactions 6.3 Phase-Transfer and Ion-Pairing Catalysis of Pentanidiums and Bisguanidiniums7. HALOGEN, CHALCOGEN7.1 Halogen, Chalcogen, Anion-pi Bonding and sigma-Hole Interactions in Catalysis 7.2 Halogen Bonding in Organic Synthesis and Organocatalysis7.3 Chalcogen Bonding: An Overview8. SULFUR YLIDES9. CHIRAL HYPERVALENT IODINES: ACTIVE PLAYERS IN ASYMMETRIC SYNTHESIS10. LEWIS BASE CATALYSIS PROMOTED NUCLEOPHILIC SUBSTITUTIONS - RECENT ADVANCES AND FUTURE DIRECTIONS11. ACTIVATING PRONUCLEOPHILES WITH HIGH PK(A) VALUES: CHIRAL ORGANO-SUPERBASES12. RECENT ADVANCES IN THE CHEMISTRY AND APPLICATIONS OF N-HETEROCYCLIC CARBENES13. ENANTIOSELECTIVE REDOX AND RADICAL REACTIONS IN THE DARK BY CHIRAL CATALYSTS14. ORGANOCATALYSIS IN INERT C-H BOND FUNCTIONALIZATION15. ENANTIOSELECTIVE DESYMMETRIZATION REACTIONS IN ASYMMETRIC CATALYSIS16. TWO AND MORE CATALYSTS SYSTEMS16.1 Two and Multi-organocatalyst Systems 16.2 Combined Power of Organo- and Transition Metal Catalysis in Organic Synthesis 16.3 Asymmetric Reactions Enabled by Cooperative Enantioselective Amino- and Lewis Acid Catalysis 16.4 Organocatalysis and Biocatalysis Hand in Hand: Combining Catalysts in One-Pot Procedures17. RECENT PROGRESS IN ORGANOCATALYTIC ASYMMETRIC DOMINO TRANSFORMATIONS18. MULTICOMPONENT AND MULTICATALYTIC REACTIONS - A SYNTHETIC STRATEGY INSPIRED BY NATURE19. STEREODIVERGENT ASYMMETRIC SYNTHESIS VIA ORGANOCATALYSIS20. CATALYSTS RECOVERY STRATEGIES20.1 Fluorous organocatalysis20.2 Covalently Supported Ionic Liquid Phases: An Advanced Class of Recyclable Catalytic Systems20.3 Polymer Supported organocatalysts21. SUPRAMOLECULAR CATALYSIS21.1 Harnessing DNA as a Designable Scaffold for Asymmetric Catalysis: Recent Advances and Future Perspectives21.2 Chitosan Based Catalyst and Their Mode of Action21.3 Functionalized Macrocycles in Supramolecular Organocatalysis21.4 Nanopores of a Covalent Organic Framework: A Customizable Vessel for Organocatalysis21.5 Asymmetric Catalysis Under 1D/2D Nanostructured Materials21.6 Synthesis of Chiral Polymer Catalysts and Their Application to Asymmetric Reactions21.7 Stable, crystalline, porous, covalent organic frameworks as a platform for chiral organocatalysts21.7 Enabling protein-hosted organocatalytic transformations22. SITE SELECTIVE AND REMOTE FUNCTIONALIZATION22.1 Recent advances in site-selective functionalization of carbohydrates mediated by organocatalysts22.2 N-Heterocyclic Carbene Catalysis via Azolium Dienolates: An Efficient Strategy for Remote Enantioselective Functionalizations22.3 Advances in Organocatalytic 1,6-Addition Reactions: Enantioselective Construction of Remote Stereogenic Centers22.4 Site-selective reactions mediated by molecular containers23. NON-CONVENTIONAL ACTIVATION METHODS23.1 Mechanochemical Organocatalysis: Do High Enantioselectivities Contradict What We Might Expect?23.2 Microwave-assisted Organo-catalyzed C-C and C-X (Heteroatom) Bond-forming Reactions23.3 Modern Electrochemical Aspects for the Synthesis of Value-Added Organic Products24. ORGANOCATALYSIS IN NON-CONVENTIONNAL MEDIAS24.1 Organocatalysis in aqueous media24.2 Chiral Ionic Liquids and Deep Eutectic Solvents in Asymmetric Synthesis 24.3 Application of Biobased Solvents in Asymmetric Catalysis25. LIGHT IN ORGANOCATALYSIS25.1 Recent Trends in Photocatalytic Enantioselective Reactions25.2 Organophotoredox catalysis : reactions and Structure-Property Relationships of catalysts 25.3 Photoredox Dual Catalysis26. SWITCHABLE CATALYSTS : DYNAMIC RESPONSIVE SYSTEMS FOR CATALYTIC FUNCTION27. EMERGING SYSTEMS27.1 Bio-Inspired Quinone Catalysis27.2 Taurine: A Water Friendly Organocatalyst in Organic Reactions27.3 Vitamin B1: A Versatile Organocatalyst for Organic Synthesis27.4 Growing Impact of Carbohydrate-Based Organocatalysts28. COMPUTATIONAL INSIGHTS28.1 The Central Role of Nonbonding Interactions in Modern Covalent Organocatalysis28.2 Transition State Models for Understanding the Origin of Chiral Induction in Asymmetric Catalysis28.3 Catalyst Design Within Asymmetric Organocatalysis29. APPLIED ORGANOCATALYSIS29.1 Low-loading asymmetric organocatalysis29.2 Asymmetric organocatalysis: an enabling technology for medicinal chemistry29.3 New chemical processes to streamline carbohydrate synthesis29.4 Organocatalytic Asymmetric Methodologies towards the Synthesis of Atropisomeric N-Heterocycles29.5 Catalytic Enantioselective Construction of Spiro Quaternary Carbon Stereocenters29.6 Organocatalyzed Asymmetric Synthesis of Axially, Planar, and Helical Chiral Compounds29.7 Recent Advances in Organocatalytic Kinetic Resolution for the Synthesis of Functionalized Products29.8 Recent applications of asymmetric organocatalytic annulation reactions in natural product synthesis29.9 Green chemistry meets medicinal chemistry: a perspective on modern metal-free late-stage functionalization reactions29.10 Synthesis of Cyclic Fragrances29.11 Organocatalytic Atroposelective Synthesis of N-N Axially Chiral Indoles and Pyrroles by De Novo Ring Formation29.12 Macromolecular architectures through organocatalysis29.13 Flow Chemistry: Recent Developments in the Synthesis of Pharmaceutical Products29.14 Asymmetric Organocatalytic Tandem/Domino Reactions to Access Bioactive Products29.15 Synthesis of radio isotope labelled products with organocatalysis30. VALORIZATION OF WASTE: SUSTAINABLE ORGANOCATALYSTS FROM RENEWABLE RESOURCES31. HIGHLIGHTS OF THE RECENT PATENT LITERATURE: FOCUS ON ASYMMETRIC ORGANOCATALYSIS