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The electrochemical storage of energy has become essential in assisting the development of electrical transport and use of renewable energies. French researchers have played a key role in this domain but Asia is currently the market leader. Not wanting to see history repeat itself, France created the research network on electrochemical energy storage (RS2E) in 2011. This book discusses the launch of RS2E, its stakeholders, objectives, and integrated structure that assures a continuum between basic research, technological research and industries. Here, the authors will cover the technological advances as well as the challenges that must still be resolved in the field of electrochemical storage, taking into account sustainable development and the limited time available to us.
Jean-Marie Tarascon is Professor at Collège de France, Paris, France and part of a research group that focuses on new sustainable batteries using abundant elements as well as promising systems such as lithium-air batteries.Patrice Simon is Professor at University Paul Sabatier, Toulouse, France. He is affiliated with the CIRIMAT laboratory (UMR 5085) where he mainly researches supercapacitors (improved energy density, etc.).
INTRODUCTION viiCHAPTER 1. BATTERIES AND SUPERCAPACITORS: SOME REMINDERS 11.1. Main evolution of batteries from the 1980s to now 11.2. Supercapacitors: recent developments 8CHAPTER 2. ADVANCED LI-ION 112.1. Positive electrode materials for Li-ion technology 112.2. Negative electrode materials for Li-ion technology 142.3. The question of electrolytes for Li-ion technology 15CHAPTER 3. CAPACITIVE STORAGE 173.1. Carbonated materials for capacitive storage 173.2. Pseudocapacitive materials 183.3. Electrolytes for supercapacitors 203.4. Hybrid systems and middle-term goals 21CHAPTER 4. NEW CHEMISTRIES 234.1. Li-air technology 244.2. Li-S technology 274.3. Na-ion technology 294.4. Redox-flow technology 324.5. All-solid state batteries 36CHAPTER 5. ECO-COMPATIBLE STORAGE 415.1. Ionothermal synthesis 425.2. Bioinspired synthesis/approach 425.3. Organic electrodes for “green” Li-ion batteries and more durable batteries 455.4. Recycling and LCA 47CHAPTER 6. SMART MATERIALS 496.1. Photonics of insertion materials to create photo-rechargeable batteries 506.2. Micro-energy sources 51CHAPTER 7. TECHNOLOGY TRANSFER, RESEARCH PROMOTION AND EDUCATION 537.1. Development: industrial property 537.2. Education 547.2.1. Erasmus Mundus Master’s degree: Materials for Energy Storage and Conversion (MESC) 557.2.2. Specialization in Energy Storage and Conversion (SCE), at ENSCBP (Bordeaux – INP) 57CONCLUSION 59BIBLIOGRAPHY 63INDEX 75