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Neutral reactive intermediates - radicals, carbenes, nitrenes, and arynes - have an interesting place within the history of organic chemistry. Once regarded as curiosities, then intensively studied from the mechanistic point of view by physical organic chemists, they now play a key role in synthetic chemistry. This concise text concentrates on the last aspect of reactive intermediate chemistry; the important reactions of these electron-deficient species are laid out clearly and simply, with carefully chosen examples illustrating their use in organic synthesis. Each chapter includes a few problems as well as suggestions for further reading and provides undergraduates with an invaluable summary of this important topic in organic chemistry.
Introduction; Radical reactions in synthesis; Carbenes; Nitrenes; Arynes; Index.
'This concise text concentrates on the last aspect of reactive intermediate chemistry; the important reactions of these electron-deficient species are laid out clearly and simply, with carefull chosen examples illustrating their use in organic synthesis. Each chapter includes a few problems as well as suggestions with an invaluable summary of this important topic in organic chemistry.'Flash Technique
John Saunders, California) Saunders, John (Vice President of Chemistry, Neurocrine Biosciences, San Diego, California, Vice President of Chemistry, Neurocrine Biosciences, San Diego
Martin Grossel, Oxford) Grossel, Martin (Senior Lecturer in Chemistry, University of Southampton; and Lecturer and Ordinary Student in Organic Chemistry, Senior Lecturer in Chemistry, University of Southampton; and Lecturer and Ordinary Student in Organic Chemistry, Christ Church
Jeremy Robertson, Oxford) Robertson, Jeremy (University Lecturer in Organic Chemistry and Fellow, University Lecturer in Organic Chemistry and Fellow, Brasenose College
Grant Ritchie, Devinder Sivia, Oxford) Ritchie, Grant (Stipendiary Lecturer in Physical Chemistry, Stipendiary Lecturer in Physical Chemistry, Magdalen College, Oxford) Sivia, Devinder (, Rutherford Appleton Laboratory and St. John's College